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Effect of Aniline Oligomers in Aniline Chemical Oxidative Polymerization on Polyaniline Supramolecular Structures

  • FUNCTIONAL POLYMERS
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Abstract

Generally, aniline oligomers are responsible for the self-assembly that guides the growth of polyaniline supramolecular structures. Therefore, they are important to elucidate the role of oligomers in aniline chemical oxidative polymerization system. In this study, we separated the main aniline oligomer components produced by the oxidation of aniline in aqueous solution by using thin-layer chromatography to ensure that the oligomers formed in the aniline chemical oxidative polymerization system. Then, these oligomers were introduced into the chemical oxidative polymerization of aniline with different acidities, and the relationship between oligomers and polyaniline supramolecular structures was investigated. The findings obtained provide useful clues for uncovering the formation mechanism of polyaniline supramolecular structures and the role of oligomers in the chemical oxidative polymerization process.

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ACKNOWLEDGMENTS

The author gratefully acknowledges the support of Prof. Xinli Jing and the research group of functional polymers in Xi’an Jiaotong University.

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Authors and Affiliations

  1. School of Chemistry, Xi’an Jiaotong University, 710049, Xi’an, China

    Jing Tao

  2. Department of Chemical Technology, Xinjiang Career Technical College, 833200, Kuitun, China

    Jing Tao, Chunyan Men & Guofeng Li

  3. Institute of Applied Chemistry, College of Chemistry, XinJiang University, 830046, Urumqi, China

    Tao Wang

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  1. Jing Tao
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  2. Tao Wang
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  4. Guofeng Li
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Jing Tao, Wang, T., Men, C. et al. Effect of Aniline Oligomers in Aniline Chemical Oxidative Polymerization on Polyaniline Supramolecular Structures. Polym. Sci. Ser. B 64, 454–463 (2022). https://doi.org/10.1134/S1560090422700178

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  • DOI: https://doi.org/10.1134/S1560090422700178

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