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Synthesis of Strong Anion Exchangers by the Interaction of 4-Vinylpyridine with Epoxy-Containing Alkylating Reagents and Their Use in the Sorption of Noble Metals

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Abstract

Methods of obtaining strong anion exchangers provided with oxygen-containing functional groups (–OH, C–O–C), along with pyridinium cations, were described. Spontaneous polymerization of monomeric 4-vinylpyridine under its alkylation with polyfunctional epoxides, epichlorohydrin and bis-glycidyl ethers, in a polymer solvating medium was used. The sorbents obtained are effective in the analysis of mixtures of complex noble metal ions and their sorption from multicomponent solutions in mineral acids.

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ACKNOWLEDGMENTS

We are grateful to the Center for Study of the Molecular Structure of the Nesmeyanov Institute of Organoelement Compounds, Ministry of Science and Higher Education of the Russian Federation, for conducting the IR spectral analysis.

Funding

This study was supported by the Russian Foundation for Basic Research (project no. 20-03-00354А).

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Authors and Affiliations

  1. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 119991, Moscow, Russia

    L. A. Pavlova, E. G. Kononova, S. E. Lyubimov & V. A. Davankov

  2. Moscow State University, Chemical Faculty, 119899, Moscow, Russia

    Y. A. Maksimova

Authors
  1. L. A. Pavlova
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  2. E. G. Kononova
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  3. Y. A. Maksimova
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  4. S. E. Lyubimov
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  5. V. A. Davankov
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Corresponding author

Correspondence to S. E. Lyubimov.

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The authors declare that they have no conflicts of interest.

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Translated by L. Barbanel

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Pavlova, L.A., Kononova, E.G., Maksimova, Y.A. et al. Synthesis of Strong Anion Exchangers by the Interaction of 4-Vinylpyridine with Epoxy-Containing Alkylating Reagents and Their Use in the Sorption of Noble Metals. Polym. Sci. Ser. B 64, 470–478 (2022). https://doi.org/10.1134/S1560090422700087

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  • DOI: https://doi.org/10.1134/S1560090422700087

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