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Self-Peristaltic Gel-Microspheres Based on Carboxymethyl Cellulose and Polyacrylic Acid Prepared via Inverse Suspension for Recovery Rare Earth Ions from Aqueous Solution

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Abstract

In this study, cross-linked microspheres formed by interpenetrating networks of carboxymethyl cellulose and polyacrylic acid were prepared via inverse-suspension polymerization. The resultant has high adsorption capacity for rare earth ions, can reach 313 mg/g for Ce3+ under the condition of pH 6 at normal temperature. Unique self-creep characteristic gives it a fast-speed adsorption performance, which makes it to reach adsorption equilibrium within 70 min. It also has good reuse performance; its adsorption capacity decrease rate is only 21% after six adsorption–desorption cycles. Adsorption kinetics and thermodynamic studies and adsorption isothermal analysis were researched as well. The research conclusion suggested that this adsorbent is a promising adsorbent for recovering the rare earth ions from wastewater containing rare earth. And all related experiments show that ISP method is effective for making spherical macromolecular adsorbents via water-soluble monomers.

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Funding

The authors acknowledge precious support provided by the National Natural Science Fund of “Study on the Control of Catalytic Ozonation and Bromate Formation by Surface Performance Regulation of Fe–Co/Mn Based Catalysts (no. 2018033022),” and the fund of “Study on Preparation and Performance of Biomass Macromolecular Composites (no. 2017036019).”

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  1. Faculty of Materials Science and Chemistry, China University of Geosciences, 430074, Wuhan, China

    Yang Cai, Wenjun Luo, Jinlong Mu, Tiantian Luo, Jin Wei & Yunlong Xiao

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  1. Yang Cai
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  2. Wenjun Luo
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Correspondence to Wenjun Luo.

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Yang Cai, Luo, W., Mu, J. et al. Self-Peristaltic Gel-Microspheres Based on Carboxymethyl Cellulose and Polyacrylic Acid Prepared via Inverse Suspension for Recovery Rare Earth Ions from Aqueous Solution. Polym. Sci. Ser. B 62, 522–533 (2020). https://doi.org/10.1134/S1560090420050024

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