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Azidopyrazole as Initiator for Ethylene Carbonate Ring Opening Polymerization

Polymer Science, Series B volume 61, pages 735–742 (2019)Cite this article

Abstract

A green approach for ethylene carbonate ring opening polymerization was proposed via an interaction between ethylene carbonate and 5-azido-3-methyl-1-phenyl-1H-pyrazole-4-carbaldehyde (azidopyrazole) in presence of FeCl3 anhydrous as initiator. Despite the high thermodynamic stability of ethylene carbonate, reducing consumption of heat and time has been obtained. The effect of the molar ratio of azidopyrazole to ethylene carbonate has been studied and the resulted products were characterized.

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Authors and Affiliations

  1. Department of Polymer and Pigments Technology, Chemical Industries Research Division, National Research Centre, Giza, Egypt

    Rasha A. Baseer

  2. Organometallic and Organometalloid Chemistry Department, Chemical Industries Research Division, National Research Centre, Giza, Egypt

    Ewies F. Ewies, Marwa El-Hussieny & Naglaa F. El-Sayed

  3. Department of Packing and Packaging Materials, Chemical Industries Research Division, National Research Centre, Giza, Egypt

    Abou Elfetouh A. Abdelhakim

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  1. Rasha A. Baseer
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  2. Ewies F. Ewies
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  3. Marwa El-Hussieny
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  4. Naglaa F. El-Sayed
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  5. Abou Elfetouh A. Abdelhakim
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Correspondence to Rasha A. Baseer.

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Baseer, R.A., Ewies, E.F., El-Hussieny, M. et al. Azidopyrazole as Initiator for Ethylene Carbonate Ring Opening Polymerization. Polym. Sci. Ser. B 61, 735–742 (2019). https://doi.org/10.1134/S1560090419060034

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  • DOI: https://doi.org/10.1134/S1560090419060034

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