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Oxidative Destruction of Chitosan and Its Stability

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Abstract

The properties of chitosan degraded under hydrogen peroxide action is studied. Using FTIR spectroscopy, HPLC, and 13C NMR spectroscopy, it is found that the oxidative destruction of chitosan is accompanied by the crosslinking reactions leading to formation of the insoluble fraction of polymer. The mechanism of the crosslinking process and production of chitosan capable of maintaining solubility for a long time are discussed.

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ACKNOWLEDGMENTS

This work was carried out with the use of equipment of the Analytical Center of Collective Use of the Institute of Problems of Chemical Physics, Russian Academy of Sciences, within the scope of the State Task (state registration no. 0121056328).

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Authors and Affiliations

  1. Institute of Problems of Chemical Physics (Chernogolovka Branch), Russian Academy of Sciences, 142432, Chernogolovka, Moscow oblast, Russia

    B. A. Komarov, G. V. Malkov, S. G. Vasil’ev, S. A. Baskakov, G. A. Estrina, L. L. Gur’eva & V. I. Volkov

  2. All-Russian Research and Technological Institute of Biological Industry, 141113, Shchelkovo, Moscow oblast, Russia

    M. A. Frolova & A. I. Albulov

Authors
  1. B. A. Komarov
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  2. G. V. Malkov
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  3. S. G. Vasil’ev
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  4. S. A. Baskakov
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  5. G. A. Estrina
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  6. L. L. Gur’eva
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  7. V. I. Volkov
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  8. M. A. Frolova
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  9. A. I. Albulov
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Correspondence to B. A. Komarov.

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Translated by K. Aleksanyan

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Komarov, B.A., Malkov, G.V., Vasil’ev, S.G. et al. Oxidative Destruction of Chitosan and Its Stability. Polym. Sci. Ser. B 61, 189–199 (2019). https://doi.org/10.1134/S1560090419020039

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  • DOI: https://doi.org/10.1134/S1560090419020039

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