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Synthesis and Metathesis Polymerization of Cycloadduct Based on Quadricyclane and Perfluoro-1-octene

Polymer Science, Series B volume 61, pages 387–394 (2019)Cite this article

Abstract

Previously undescribed norbornene monomer 3,3,4-trifluoro-4-perfluorohexyltricyclononene-7 is synthesized by the [2+2+2] cycloaddition reaction. The monomer is involved in the ring-opening polymerization metathesis in the presence of the first-generation Grubbs catalyst to give rise to the amorphous, glassy unsaturated polymer. The gas-transport properties of the metathesis polymer is studied, the gas permeability and diffusion coefficients for a wide range of gases (He, H2, O2, N2, CO2, CH4) are determined, and the solubility coefficients of gases in this polymer are calculated.

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FUNDING

This work was supported by the Russian Science Foundation, project 17-73-10499.

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Authors and Affiliations

  1. A.V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, 119991, Moscow, Russia

    G. O. Karpov, D. S. Bakhtin, M. V. Bermeshev, I. L. Borisov, B. A. Bulgakov, V. V. Volkov & E. Sh. Finkelstein

  2. D.I. Mendeleev University of Chemical Technology, 125047, Moscow, Russia

    M. V. Bermeshev

  3. Faculty of Chemistry, M.V. Lomonosov Moscow State University, 119991, Moscow, Russia

    B. A. Bulgakov

Authors
  1. G. O. Karpov
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  2. D. S. Bakhtin
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  3. M. V. Bermeshev
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  4. I. L. Borisov
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  5. B. A. Bulgakov
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  6. V. V. Volkov
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  7. E. Sh. Finkelstein
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Corresponding author

Correspondence to M. V. Bermeshev.

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Translated by T. Soboleva

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Karpov, G.O., Bakhtin, D.S., Bermeshev, M.V. et al. Synthesis and Metathesis Polymerization of Cycloadduct Based on Quadricyclane and Perfluoro-1-octene. Polym. Sci. Ser. B 61, 387–394 (2019). https://doi.org/10.1134/S1560090419020027

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  • DOI: https://doi.org/10.1134/S1560090419020027

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