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Green Copolymerization of Limonene with β-Pinene Catalyzed by an Eco-Catalyst Maghnite-H+

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Abstract

In this paper, we report a simple method for preparation of poly(limonene-co-β–pinene) using green and low cost catalyst. Copolymers were synthesized by cationic copolymerization by using H+ exchanged Maghnite as a catalyst (Montmorillonite type clay). Several parameters affecting the copolymerization were investigated such as the reaction kinetics, effect of temperature, catalyst mass and effect of monomer feed ratio. The copolymerization in solution leads to the yield 40.5% at −5°C for a reaction time of 6 h. The structure of the obtained copolymer is confirmed by IR and 1H NMR spectroscopy, and differential scanning calorimetry. Finally, a new method for the preparation of poly(limonene-co-β-pinene) in short reaction time was developed, in order to respect the principles of a green chemistry.

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Authors and Affiliations

  1. Laboratory of Polymer Chemistry, Department of Chemistry, Faculty of Exact and Applied Sciences, University of Oran-1, Ahmed Benbella. BP N° 1524 El M’Naouar, Oran, 31000, Algeria

    H. Derdar, M. Belbachir, F. Hennaoui, M. Akeb & A. Harrane

  2. Department of Chemistry, Faculty FSEI, University Abdelhamid Ibn Badis, Mostaganem, Algeria

    A. Harrane

Authors
  1. H. Derdar
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  2. M. Belbachir
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  3. F. Hennaoui
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  4. M. Akeb
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  5. A. Harrane
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Correspondence to H. Derdar.

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Derdar, H., Belbachir, M., Hennaoui, F. et al. Green Copolymerization of Limonene with β-Pinene Catalyzed by an Eco-Catalyst Maghnite-H+. Polym. Sci. Ser. B 60, 555–562 (2018). https://doi.org/10.1134/S1560090418050056

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  • DOI: https://doi.org/10.1134/S1560090418050056

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