Skip to main content
SpringerLink
Log in

Effects of Various Amounts of New Hepta-Ether as the Internal Donor on the Polymerization of Propylene with and without the External Donor

Polymer Science, Series B volume 59, pages 639–649 (2017)Cite this article

Abstract

The new hepta-ether compound as the internal donor was synthesized using the Williamson reaction of dipentaerythritol with sodium hydride as the strong base and iodomethane as the alkyl halide. The hepta-ether compound was characterized by NMR, FTIR, and GC techniques. The MgCl2-supported catalysts incorporated with different amounts of hepta-ether compound as the internal donor and without the internal donor were synthesized and characterized. The propylene polymerization was carried out using these catalysts in the presence of triethylaluminum as a co-catalyst and hydrogen as a chain transfer agent, with and without the external donor. The effect of a new internal donor on propylene polymerization using prepared MgCl2-supported Ziegler-Natta catalysts was investigated.

This is a preview of subscription content, access via your institution.

Access options

Buy single article

Instant access to the full article PDF.

USD 39.95

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

References

  1. E. Albizzati and M. Galimberti, Catal. Today 41,159 (1998).

    Article  CAS  Google Scholar 

  2. J. Pater, G. Weickert, and W. P. van Swaaij, Chem. Eng. Sci. 57, 3461 (2002).

    Article  CAS  Google Scholar 

  3. L. Zhang, Z. Fu, and Z. Fan, Macromol. Res. 18, 695 (2010).

    Article  CAS  Google Scholar 

  4. K. Thushara, E. S. Gnanakumar, R. Mathew, T. Ajithkumar, P. Rajamohanan, S. Bhaduri, and C. S. Gopinath, Dalton Trans. 41,11311 (2012).

    Article  CAS  Google Scholar 

  5. J. Kumawat, V. Kumar Gupta, and K. Vanka, Eur. J. Inorg. Chem. 2014, 5063 (2014).

    Article  CAS  Google Scholar 

  6. N. Kashiwa, J. Polym. Sci., Part A: Polym. Chem. 42, 1 (2004).

    Article  CAS  Google Scholar 

  7. A. Lima, A. P. Azeredo, M. Nele, S. Liberman, and J. C. Pinto, Macromol. Symp. 344, 86 (2014).

    Article  CAS  Google Scholar 

  8. E. Groppo, K. Seenivasan, and C. Barzan, Catal. Sci. Technol. 3, 858 (2013).

    Article  CAS  Google Scholar 

  9. A. Bazhenov, M. Linnolahti, T. A. Pakkanen, P. Denifl, and T. Leinonen, J. Phys. Chem. C 118, 4791 (2014).

    Article  CAS  Google Scholar 

  10. T. B. Mikenas, E. I. Koshevoy, V. A. Zakharov, and M. I. Nikolaeva, Macromol. Chem. Phys. 215, 1707 (2014).

    Article  CAS  Google Scholar 

  11. E. S. Gnanakumar, R. R. Gowda, S. Kunjir, T. Ajithkumar, P. Rajamohanan, D. Chakraborty, and C. S. Gopinath, ACS Catal. 3, 303 (2013).

    Article  CAS  Google Scholar 

  12. D. V. Stukalov, V. A. Zakharov, A. G. Potapov, and G. D. Bukatov, J. Catal. 266, 39 (2009).

    Article  CAS  Google Scholar 

  13. A. G. Potapov and L. V. Politanskaya, J. Mol. Catal. A: Chem. 368–369, 159 (2013).

    Article  Google Scholar 

  14. K. Tangjituabun, B. Jongsomjit, and P. Praserthdam, Catal. Lett. 109, 147 (2006).

    Article  CAS  Google Scholar 

  15. A. S. Bazhenov, P. Denifl, T. Leinonen, A. Pakkanen, M. Linnolahti, and T. A. Pakkanen, J. Phys. Chem. C 118, 27878 (2014).

    Article  CAS  Google Scholar 

  16. P. Li, S. Tu, T. Xu, Z. Fu, and Z. Fan, J. Appl. Polym. Sci. 132, 41689 (2015).

    Google Scholar 

  17. T. Taniike, T. Wada, I. Kouzai, S. Takahashi, and M. Terano, Macromol. Res. 18, 839 (2010).

    Article  CAS  Google Scholar 

  18. F. Capone, L. Rongo, M. D’Amore, P. H. Budzelaar, and V. Busico, J. Phys. Chem. C 117, 24345 (2013).

    Article  CAS  Google Scholar 

  19. J. C. Chadwick, G. Morini, G. Balbontin, I. Camurati, J. J. Heere, I. Mingozzi, and F. Testoni, Macromol. Chem. Phys. 202, 1995 (2001).

    Article  CAS  Google Scholar 

  20. D. Ribour, R. Spitz, and V. Monteil, J. Polym. Sci., Part A: Polym. Chem. 48, 2631 (2010).

    Article  CAS  Google Scholar 

  21. T. Taniike and M. Terano, J. Catal. 293, 39 (2012).

    Article  CAS  Google Scholar 

  22. J. Qiao, M. Guo, L. Wang, D. Liu, X. Zhang, L. Yu, W. Song, and Y. Liu, Polym. Chem. 2, 1611 (2011).

    Article  CAS  Google Scholar 

  23. M. D. F. V. Marques, R. D. S. Cardoso, and M. G. da Silva, Appl. Catal. A 374, 65 (2010).

    Article  CAS  Google Scholar 

  24. T. Yono, T. Inoue, S. Ikai, M. Tamura, and M. Shimizu. Eur. Polym. J. 22, 637 (1986).

    Article  Google Scholar 

  25. J. C. W. Chien, Y. Hu, and J. C. Vizzini. J. Polym. Sci., Part A: Polym. Chem. 28, 273 (1990).

    Article  CAS  Google Scholar 

  26. K. Soga, T. Shiono, and Y. Doi, Makromolek. Chem. 189, 1531 (1988).

    Article  CAS  Google Scholar 

  27. P. Pino and R. Mulhaupt. Angew. Chem. 19, 857 (1980).

    Article  Google Scholar 

  28. P. C. Barb, G. Cecchin, and L. Noristi, Adv. Polym. Sci. 81, 1 (1987).

    Google Scholar 

  29. R. Zahedi, F. Afshar Taromi, S. H. Mirjahanmardi, M. Nekoomanesh Haghighi, K. Jadidi, and R. Jamjah, Adv. Polym. Technol. (2015) (in press). doi 10.1002/adv.21651

    Google Scholar 

  30. R. Zahedi, F. Taromi, S. H. Mirjahanmardi, M. N. Haghighi, K. Jadidi, and R. Jamjah, Chin. J. Polym. Sci. 34, 268 (2016).

    Article  CAS  Google Scholar 

  31. S. H. Mirjahanmardi, F. Afshar Taromi, R. Zahedi, M. Nekoomanesh Haghighi, R. Jamjah, and Gh. Jafari Asl, Polym. Sci., Ser. B 58 (6), 619 (2016).

    Article  CAS  Google Scholar 

  32. R. Zahedi, F. Afshar Taromi, S. H. Mirjahanmardi, M. Nekoomanesh Haghighi, K. Jadidi, and R. Jamjah, Polym. Sci., Ser. B 58 (2), 143 (2016).

    Article  CAS  Google Scholar 

  33. B. G. Song, Y. H. Choi, and S.-K. Ihm, J. Appl. Polym. Sci. 130, 851 (2013).

    Article  CAS  Google Scholar 

  34. H. Hamaki, W. Hirahata, Y. Fujiwara, S. Kimata, H. Hama, and K. Ikeda, US Patent No. 2013/0109789A1 (2013).

    Google Scholar 

  35. R. Zahedi, F. Afshar-Taromi, S. H. Mirjahanmardi, M. Nekoomanesh-Haghighi, Kh. Jadidi, and R. Jamjah, Chin. J. Polym. Sci. 34 (3), 268.

  36. B. G. Song and S.-K. Ihm, J. Appl. Polym. Sci. 131, 40536 (2014).

    Article  Google Scholar 

  37. N. Cui, Y. Ke, H. Li, Z. Zhang, C. Guo, Z. Lv, and Y. Hu, J. Appl. Polym. Sci. 99, 1399 (2006).

    Article  CAS  Google Scholar 

  38. L. Lu, H. Niu, and J. Y. Dong, J. Appl. Polym. Sci. 124, 1265 (2012).

    Article  CAS  Google Scholar 

  39. B. Chen, Q.-F. Zhang, L.-P. Zhao, X.-Q. Zhang, and H.-X. Zhang, Polym. Bull. 70, 2793 (2013).

    Article  CAS  Google Scholar 

  40. K. M. Bichinho, G. P. Pires, J. H. Z. dos Santos, M. M. de Camargo Forte, and C. R. Wolf, Anal. Chim. Acta 512, 359 (2004).

    Article  CAS  Google Scholar 

  41. T. Taniike, T. Funako, and M. Terano, J. Catal. 311, 33 (2014).

    Article  CAS  Google Scholar 

  42. U. C. Makwana, K. J. Singala, R. B. Patankar, S. C. Singh, and V. K. Gupta, J. Appl. Polym. Sci. 125, 896 (2012).

    Article  CAS  Google Scholar 

  43. H. Chang, H. Li, T. Zheng, Q. Zhou, L. Zhang, and Y. Hu, J. Polym. Res. 21, 554 (2014).

    Article  Google Scholar 

  44. Q. Zhou, T. Zheng, H. Li, Q. Li, Y. Zhang, L. Zhang, and Y. Hu, Ind. Eng. Chem. Res. 53, 17929 (2014).

    Article  CAS  Google Scholar 

  45. G. Bukatov, S. Sergeev, V. Zakharov, and A. Potapov, Kinet. Catal. 49, 782 (2008).

    Article  CAS  Google Scholar 

  46. N. Chumachenko, V. Zakharov, G. Bukatov, and S. Sergeev, Appl. Catal., A 469, 512 (2014).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Polymer Engineering, Amirkabir University of Technology-Mahshahr Campus, Mahshahr, 63516-43659, Iran

    Seyed Heidar Mirjahanmardi

  2. Department of Polymer Engineering, Amirkabir University of Technology, Tehran, 15875-4413, Iran

    Faramarz Afshar Taromi

  3. Department of Chemistry, Amirkabir University of Technology, Tehran, 15875-4413, Iran

    Roya Zahedi

  4. Iran Polymer and Petrochemical Institute (IPPI), Tehran, 14977-13115, Iran

    Mehdi Nekoomanesh Haghighi

Authors
  1. Seyed Heidar Mirjahanmardi
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Faramarz Afshar Taromi
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Roya Zahedi
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Mehdi Nekoomanesh Haghighi
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Faramarz Afshar Taromi.

Additional information

The article is published in the original.

Rights and permissions

Reprints and Permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Mirjahanmardi, S.H., Taromi, F.A., Zahedi, R. et al. Effects of Various Amounts of New Hepta-Ether as the Internal Donor on the Polymerization of Propylene with and without the External Donor. Polym. Sci. Ser. B 59, 639–649 (2017). https://doi.org/10.1134/S1560090417060069

Download citation

  • Received:

  • Revised:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1560090417060069

search

Navigation