Abstract
New regulators of radical polymerization of methyl methacrylate based on N-(aryl)-o-iminoquinones of various structures are proposed. It is shown that samples of polymethylmethacrylate with the participation of N-(aryl)-o-iminobenzoquinones could be used as macroinitiators of polymerization. Optimal conditions to synthesize polymers in the presence of o-iminobenzoquinones are determined, which make it possible to obtain polymethylmethacrylate with a polydispersity coefficient of no more than 1.5 on deep conversions during bulk polymerization.
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Original Russian Text © L.B. Vaganova, O.S. Lizyakina, M.G. Chegerev, A.V. Piskunov, D.F. Grishin, 2017, published in Vysokomolekulyarnye Soedineniya, Seriya B, 2017, Vol. 59, No. 5, pp. 326–336.
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Vaganova, L.B., Lizyakina, O.S., Chegerev, M.G. et al. Polymerization of methyl methacrylate in the presence of o-iminoquinones: Reversible and irreversible inhibition. Polym. Sci. Ser. B 59, 506–515 (2017). https://doi.org/10.1134/S1560090417050165
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DOI: https://doi.org/10.1134/S1560090417050165