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The using of thermal analysis methods for the construction of isothermal transformation diagrams of thermosets

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Abstract

The article reviews the using of thermal analysis methods and mathematic modeling of kinetics of chemical processes for the creation of isothermal transformation diagrams of thermosetting binders. Differential scanning calorimetry (DSC), temperature modulated DSC, gel-timer and thermogravimetry are used for the construction of isothermal transformation diagrams with vitrification and gelation curves, areas of thermal stability and post-curing. The Time-Temperature-Transformation diagrams obtained can be used for optimization of time-temperature schedules for polymer matrix composites fabrication at the laboratory scale.

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Authors and Affiliations

  1. All-Russian Scientific Research Institute of Aviation Materials, ul. Radio 17, Moscow, 105005, Russia

    M. A. Khaskov

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Original Russian Text © M.A. Khaskov, 2017, published in Vysokomolekulyarnye Soedineniya, Seriya B, 2017, Vol. 59, No. 1, pp. 37–48.

The article was translated by the authors.

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Khaskov, M.A. The using of thermal analysis methods for the construction of isothermal transformation diagrams of thermosets. Polym. Sci. Ser. B 59, 51–61 (2017). https://doi.org/10.1134/S1560090417010080

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