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Doped poly(m-phenylenediamine) (PmPDA): A new precursor for Cr2O3 nanoparticles

  • Functional Polymers
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Abstract

Poly(m-phenylene diamine) has been synthesized and characterized by physical and spectral techniques. The effect of doping Cr, Co and Ni ions on the spectral, thermal and optical properties has been studied. Optical band gap measurements indicated that, doped polymers have wider optical band gap than the pure one. The effect of doping on the thermal stability differs according to the doped metal ion. The doped with Cr ions poly(m-phenylenediamine) has been used as a precursor of mesoporous Cr2O3 nanoparticles, which have been also characterized by XRD and HR-TEM.

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References

  1. G. M. Sudhana, G. Thenmozhi, D. Jayakumar, and R. Jaya Santhi, J. Chem. Pharm. Res. 4, 49 (2012).

    Google Scholar 

  2. O. Milad, Polym. Sci., Ser. B 57, 669 (2015).

    Article  Google Scholar 

  3. T. Bashir, A. Shakoor, E. Ahmad, M. Saeed, N. A. Niaz, and S. K. Tirmizi, Polym. Sci., Ser. B 57, 257 (2015).

    Article  CAS  Google Scholar 

  4. S. Simplicio, E. F. Lucas, M. A. S. Costa, L. C. Costa, and L. Claudio de Santa Maria, J. Therm. Anal. Calorim. 117, 369 (2014).

    CAS  Google Scholar 

  5. W. Yu, L. Zhang, H. Wang, and L. Chai, J. Hazard. Mater. 260, 789 (2013).

    Article  CAS  Google Scholar 

  6. P. Sang, Y. Wang, L. Zhang, L. Chai, and H. Wang, Trans. Nonferrous Met. Soc. China 23, 243 (2013).

    Article  CAS  Google Scholar 

  7. C. M. Gupta and S. S. Umare, Macromolecules 25, 138 (1992).

    Article  CAS  Google Scholar 

  8. S. K. Ujjain, P. Ahuja, R. K. Sharma, and G. Singh, Int. J. Chem. 7, 69 (2015).

    Article  CAS  Google Scholar 

  9. N. M. Hosny, N. Nowesser, A. S. Al Hussaini, and M. Sh. Zoromba, J. Inorg. Organomet. Polym. 26, 41 (2016)

    Article  CAS  Google Scholar 

  10. N. M. Hosny and M. Sh. Zoromba, J. Mol. Struct. 1027, 128 (2012).

    Article  CAS  Google Scholar 

  11. M. Sh. Zoromba and N. M. Hosny, J. Therm. Anal. Calorim. 119, 605 (2015).

    Article  CAS  Google Scholar 

  12. N. M. Hosny, N. Nowesser, A. S. Al Hussaini, and M. Sh. Zoromba, J. Mol. Struct. 1106, 479 (2016).

    Article  CAS  Google Scholar 

  13. N. M. Hosny, A. S. Al Hussaini, N. Nowesser, and M. Sh. Zoromba, J. Therm. Anal. Calorim. 124, 287 (2016).

    Article  CAS  Google Scholar 

  14. T. Hanemann and D. V. Szabo, Materials 3, 3468 (2010).

    Article  CAS  Google Scholar 

  15. M. Kakihana, T. Okubo, M. Arima, O. Uchiyama, M. Yashima, and M. Yoshimura, Chem. Mater. 9, 451 (1997).

    Article  CAS  Google Scholar 

  16. X. H. Zhong, S. H. Liu, Z. H. Zhang, L. Li, Z. Wei, and W. Knoll, J. Mater. Chem. 14, 2790 (2004).

    Article  CAS  Google Scholar 

  17. L. Vayssieres, K. Keis, S. E. Lindquist, and A. Hagfeldt, J. Phys. Chem. B 105, 3350 (2001).

    Article  CAS  Google Scholar 

  18. N. M. Hosny, Mater. Chem. Phys. 144, 247 (2014).

    Article  CAS  Google Scholar 

  19. X. Pang, K. Gao, and A. A. Volinsky, J. Mater. Res. 22, 3531 (2007).

    Article  CAS  Google Scholar 

  20. F. D. Lai, C. Y. Huang, C. M. Chang, L. A. Wang, and W. C. Cheng, Microelectron. Eng. 67–68, 17 (2003).

    Article  Google Scholar 

  21. E. Sourty, J. L. Sullivan, and M. D. Bijker, Tribol. Int. 36, 389 (2003).

    Article  CAS  Google Scholar 

  22. P. Hones, M. Diserens, and F. Levy, Surf. Coat. Technol. 120–121, 277 (1999).

    Article  Google Scholar 

  23. I. Amer, H. D. A. Young, and C. M. Vosloo, Eur. Polym. J. 49, 3251 (2013).

    Article  CAS  Google Scholar 

  24. B. I. Nandapure, S. B. Kondawar, M. Y. Salunkhe, and A. I. Nandapure, Adv. Mater. Lett. 4, 134 (2013).

    Article  CAS  Google Scholar 

  25. D. C. Trivedi and H. S. Nalwa, Organic Conductive Molecules Polymers, 2nd ed. (John Wiley and Sons, New York, 1997).

    Google Scholar 

  26. K. Gupta, G. Chakraborty, S. Ghatak, P. C. Jana, and A. K. Meikap, J. Appl. Polym. Sci. 115, 2911 (2010).

    Article  CAS  Google Scholar 

  27. K. Nakamoto, Infrared Spectra of Inorganic and Coordination Compounds (John Wiley, New York, 1970).

    Google Scholar 

  28. N. M. Hosny and A. M. Shalaby, Transition Met. Chem. 32, 1085 (2007).

    Article  CAS  Google Scholar 

  29. N. Nawar and N. M. Hosny, Chem. Pharm. Bull. 47, 944 (1999).

    Article  CAS  Google Scholar 

  30. N. M. Hosny, J. Mol. Struct. 923, 98 (2009).

    Article  CAS  Google Scholar 

  31. C. M. G. Henriquez, C. A. Terraza, L. H. Tagle, A. B. Gonzalez, U. G. Volkmann, A. L. Cabrera, E. Ramos-Moore, and M. J. Retamal, J. Mater. Chem. 22, 6782 (2012).

    Article  Google Scholar 

  32. P. Natkanski, P. Kustrowski, A. Bialas, and J. Surman, J. Therm. Anal. Calorim. 113, 335 (2013).

    Article  CAS  Google Scholar 

  33. E. Erdem, M. Karakisla, and M. Sacak, Eur. Polym. J. 40, 785 (2004).

    Article  CAS  Google Scholar 

  34. S. Ding, H. Mao, and W. Zhang, J. Appl. Polym. Sci. 109, 2842 (2008).

    Article  CAS  Google Scholar 

  35. A. B. P. Lever, Inorganic Electronic Spectroscopy (Elsevier, Amsterdam, 1986).

    Google Scholar 

  36. J. Tauc, R. Grigorovici, and A. Vancu, Phys. Status Solidi B 15, 627 (1966).

    Article  CAS  Google Scholar 

  37. J. Tauc, Mater. Res. Bull. 3, 37 (1968).

    Article  CAS  Google Scholar 

  38. M. L. Fu, G. C. Guo, X. Liu, L. Z. Cai, and J. S. Huang, Inorg. Chem. Commun. 8, 18 (2005).

    Article  CAS  Google Scholar 

  39. H. Klug and L. Alexander, X-ray Diffraction Procedures (Wiley, New York, 1962).

    Google Scholar 

  40. S. Ernest, Advances in Nanoporous Materials, 1st ed. (Elsevier, Amsterdam, 2009), Vol.1.

  41. N. M. Hosny, J. Therm. Anal. Calorim. 122, 89 (2015).

    Article  CAS  Google Scholar 

  42. K. Anandan and V. Rajendran, Mater. Sci. Semicond. Process. 19, 136 (2014).

    Article  CAS  Google Scholar 

  43. N. M. Hosny, Polyhedron 30, 470 (2011).

    Article  CAS  Google Scholar 

  44. N. M. Hosny and A. Dahshan, J. Mater. Chem. Phys. 137, 637 (2012).

    Article  CAS  Google Scholar 

  45. N. M. Hosny and A. Dahshan, J. Mol. Struct. 1085, 78 (2015).

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Chemistry Department, Faculty of Science, Port-Said University, 23 December Street, Port-Said, Egypt

    Nasser Mohammed Hosny, Ghada Samir, Mohamed Shafick Zoromba & Samir Alghool

  2. Department of Chemical and Materials Engineering, King Abdulaziz University, Rabigh, Saudi Arabia

    Mohamed Shafick Zoromba

  3. Department of Chemistry, Faculty of Science, Taif University, KSA 5700, Taif, Saudi Arabia

    Samir Alghool

Authors
  1. Nasser Mohammed Hosny
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  2. Ghada Samir
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  3. Mohamed Shafick Zoromba
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  4. Samir Alghool
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Correspondence to Nasser Mohammed Hosny.

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Hosny, N.M., Samir, G., Zoromba, M.S. et al. Doped poly(m-phenylenediamine) (PmPDA): A new precursor for Cr2O3 nanoparticles. Polym. Sci. Ser. B 59, 91–96 (2017). https://doi.org/10.1134/S1560090417010067

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  • DOI: https://doi.org/10.1134/S1560090417010067

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