Abstract
Postpolymerization modification of metathesis Si-containing polynorbornenes by epoxidation of double bonds of the main chain was carried out for the first time. New polynorbornenes containing one or two side Me3Si substituents in a monomer unit and oxirane fragments in the main chain were obtained and characterized. Some features of epoxidation of polynorbornenes by 1.1-dimethyldioxirane (formed in situ) or m-chloroperbenzoic acid were studied. It was shown that m-chloroperbenzoic acid was an effective epoxidation agent, which did not affect Si−C bonds in polynorbornenes. It was found that the preparation of high-molecular-weight epoxidated polynorbornenes required one to introduce an oxidation inhibitor into the reaction mixture and to perform the reaction in toluene. Chlorine-containing solvents, such as chloroform and chlorobenzene, promoted the destruction of polynorbornenes. It was shown that the introduction of oxirane fragments into the polynorbornene main chain increased its T g by 15−40°C.
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Original Russian Text © A.A. Morontsev, M.L. Gringolts, M.P. Filatova, E.Sh. Finkelshtein, 2016, published in Vysokomolekulyarnye Soedineniya, Seriya B, 2016, Vol. 58, No. 6, pp. 476–483.
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Morontsev, A.A., Gringolts, M.L., Filatova, M.P. et al. Modification of silicon-substituted polynorbornenes by epoxidation of main chain double bonds. Polym. Sci. Ser. B 58, 695–702 (2016). https://doi.org/10.1134/S1560090416060130
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DOI: https://doi.org/10.1134/S1560090416060130