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Oligomerization of N-vinylpyrroles under the action of iodine

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Abstract

The oligomerization of N-vinylpyrroles (N-vinyl-4,5,6,7-tetrahydroindole, N-vinyl-2-[1-(1-4,5,6,7-tetrahydroindole)ethyl]-4,5,6,7-tetrahydroindole, N-vinyl-2-phenylpyrrole, N-vinyl-3-heptyl-2-phenylpyrrole, N-vinyl-2,3-diphenylpyrrole, and N-vinyl-2-(2-naphthyl)pyrrole) under the action of iodine vapor leads to the formation of iodine-containing oligomers with an iodine content of 17–52% and a yield of up to 99%. The oligomers are paramagnetic and possess conductivity; they are readily soluble in organic solvents (benzene, dioxane, and chloroform) and are stable up to 110–260°C.

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Authors and Affiliations

  1. Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, ul. Favorskogo 1, Irkutsk, 664033, Russia

    M. V. Markova, I. V. Tatarinova, T. I. Vakul’skaya, S. S. Khutsishvili, G. F. Prozorova & B. A. Trofimov

  2. Institute of Macromolecular Compounds, Russian Academy of Sciences, Bolshoi pr. 31, St. Petersburg, 199004, Russia

    A. V. Yakimanskii

Authors
  1. M. V. Markova
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  2. I. V. Tatarinova
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  3. T. I. Vakul’skaya
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  4. S. S. Khutsishvili
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  5. A. V. Yakimanskii
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  6. G. F. Prozorova
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  7. B. A. Trofimov
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Corresponding author

Correspondence to B. A. Trofimov.

Additional information

Original Russian Text © M.V. Markova, I.V. Tatarinova, T.I. Vakul’skaya, S.S. Khutsishvili, A.V. Yakimanskii, G.F. Prozorova, B.A. Trofimov, 2016, published in Vysokomolekulyarnye Soedineniya, Seriya B, 2016, Vol. 58, No. 6, pp. 468–475.

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Markova, M.V., Tatarinova, I.V., Vakul’skaya, T.I. et al. Oligomerization of N-vinylpyrroles under the action of iodine. Polym. Sci. Ser. B 58, 681–688 (2016). https://doi.org/10.1134/S1560090416060117

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  • DOI: https://doi.org/10.1134/S1560090416060117

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