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A one-component photoinitiator based on 4-methylbenzophenone and morpholine

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Abstract

4-Benzoylbenzyl-3-morpholinopropanoate was synthesized, characterized and used as a one-component photoinitiator of Type II. Real-time near-IR spectroscopy was used to study the kinetics of conversion of double bonds of monomers vs. irradiation time. In this initiator, the radicals could be generated through hydrogen abstraction based on intermolecular reaction. Light intensity, concentration of initiator, and the functionality of acrylates affected the polymerization rate and the final monomer conversion.

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References

  1. Y. Yagci, S. Jockusch, and N. J. Turro, Macromolecules 43, 6245 (2010).

    Article  CAS  Google Scholar 

  2. A. Ibrahim, L. Stefano, O. Tarzi, H. Tar, C. Ley, and X. Allonas, Photochem. Photobiol. 89 (6), 1283 (2013).

    Article  CAS  Google Scholar 

  3. F. Xu, J. L. Yang, Y. S. Gong, G. P. Ma, and J. Nie, Macromolecules 45,1158 (2012).

    Article  CAS  Google Scholar 

  4. C. H. Zhou, P. R. Rajasekaran, and J. Wolff, Langmuir 26 (22), 17726 (2010).

    Article  CAS  Google Scholar 

  5. J. L. Yang, S. Q. Shi, F. Xu, and J. Nie, Photochem. Photobiol. Sci. 12, 323 (2013).

    Article  CAS  Google Scholar 

  6. D. K. Balta, N. Cetiner, G. Temel, Z. Turgut, and N. Arsu, J. Photochem. Photobiol., A 199, 316 (2008).

    Article  CAS  Google Scholar 

  7. R. Guo, Y. Gao, and M. Wu, Polymer 54, 4940 (2013).

    Article  CAS  Google Scholar 

  8. S. W. Fang, L. H. Zhang, M. Duan, and J. Zhang, Polym. Sci., Ser. B 54, 79 (2012).

    Article  CAS  Google Scholar 

  9. L. Cokbaglan, N. Arsu, Y. Yagci, S. Jockusch, and N. J. Turro, Macromolecules 36 (8), 2649 (2003).

    Article  CAS  Google Scholar 

  10. S. Jauk and R. Liska, Macromol. Rapid Commun. 26 (21), 1687 (2005).

    Article  CAS  Google Scholar 

  11. D. Tunc and Y. Yagci, Polym. Chem. 2, 2557 (2011).

    Article  CAS  Google Scholar 

  12. S. Kork, G. Yilmaz, and Y. Yagci, Macromol. Rapid Commun. 36, 923 (2015).

    Article  CAS  Google Scholar 

  13. Y. Yagci, S. Jockusch, and N. J.Turro, Macromolecules 43(15), 6245 (2010).

  14. G. Temel, D. S. Esen, and N. Arsu, Polym. Eng. Sci. 52, 133 (2012).

    Article  CAS  Google Scholar 

  15. M. V. Encinas, A. M. Rufs, T. Corrales, F. Catalina, C. Peinado, K. Schmith, M. G. Neumann, and N. S. Allen, Polymer 43, 3909 (2002).

    Article  CAS  Google Scholar 

  16. M. Aydin, N. Arsu, Y. Yagci, S. Jockusch, and N. J. Turro, Macromolecules 38 (10), 4133 (2005).

    Article  CAS  Google Scholar 

  17. T. Corrales, F. Catalina, C. Peinado, N. S. Allen, A. M. Rufs, C. Bueno, and M. V. Encinas, Polymer 43, 4591 (2002).

    Article  CAS  Google Scholar 

  18. E. Andrzejewska, D. Zych-Tomkowiak, M. Andrzejewski, G. L. Hug, B. Marciniak, Macromolecules 39 (11), 3777 (2006).

    Article  CAS  Google Scholar 

  19. H. Xie, L. H. Hu, Y. Zhang, and W. F. Shi, Prog. Org. Coat. 72, 572 (2011).

    Article  CAS  Google Scholar 

  20. D. K. Balta, N. Arsu, Y. Yagci, A. K. Sundaresan, S. Jockusch, and N. J. Turro, Macromolecules 44, 2531 (2011).

    Article  CAS  Google Scholar 

  21. K. M. Wang, K. Yang, and Q. Yu, Prog. Org. Coat. 77, 1929 (2014).

    Article  CAS  Google Scholar 

  22. J. Nie and C. N. Bowman, Biomaterials 23, 1221 (2002).

    Article  CAS  Google Scholar 

  23. T. Corrales, F. Catalina, C. Peinado, N. S. Allen, A. M. Rufs, C. Bueno, and M. V. Encinas, Polymer 43, 4591 (2002).

    Article  CAS  Google Scholar 

  24. S. K. Dogruyol, Z. Dogruyol, and N. Arsu, J. Lumin. 138, 98 (2013).

    Article  CAS  Google Scholar 

  25. M. Aydin, N. Arsu, and Y. Yagci, Macromol. Rapid Commun. 24(12), 718 (2003).

    Article  CAS  Google Scholar 

  26. K. M. Wang, Y. H. Lu, P. H. Chen, J. S. Shi, H. N. Wang, and Q. Yu, Mater. Chem. Phys. 143, 1391 (2014).

    Article  CAS  Google Scholar 

  27. G. Temel, B. Enginol, M. Aydin, D. K. Balta, and N. Arsu, J. Photochem. Photobiol., A 219 (1), 26 (2011).

    Article  CAS  Google Scholar 

  28. J. Wei and F. Liu, Macromolecules 42 (15), 5486 (2009).

    Article  CAS  Google Scholar 

  29. L. Wang, Z. Zhang, and Y. F. Ding, Soft Matter 9 (17), 4455 (2013).

    Article  CAS  Google Scholar 

  30. L. Wang and Y. F. Ding, Eur. Polym. J. 66, 99 (2015).

    Article  CAS  Google Scholar 

  31. K. M. Wang, Y. H. Lu, R. X. Yin, Y. Jiang, and Q. Yu, Polym. Sci., Ser. B 56 (2), 148 (2014).

    Article  CAS  Google Scholar 

  32. L. Wang, S. H. Maruf, D. Maniglio, and Y. F. Ding, Polymer 53 (17), 3749 (2012).

    Article  CAS  Google Scholar 

  33. D. Maniglio, Y. F. Ding, L. Wang, and C. Migliaresi, Polymer 52 (22), 5102 (2011).

    Article  CAS  Google Scholar 

  34. X. Jiang, X. Luo, and J. Yin, J. Photochem. Photobiol., A 174(2), 165 (2005).

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing, 100029, China

    Kai Jian & Jun Nie

  2. Changzhou Institute of Advanced Materials, Beijing University of Chemical Technology, Changzhou, Jiangsu, 213164, China

    Dongbing Li & Jinliang Yang

Authors
  1. Kai Jian
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  2. Jun Nie
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  3. Dongbing Li
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  4. Jinliang Yang
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Corresponding author

Correspondence to Jinliang Yang.

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Jian, K., Nie, J., Li, D. et al. A one-component photoinitiator based on 4-methylbenzophenone and morpholine. Polym. Sci. Ser. B 58, 689–694 (2016). https://doi.org/10.1134/S1560090416060099

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  • DOI: https://doi.org/10.1134/S1560090416060099

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