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Photoinduced grafting polymerization onto the surface with the use of radiation of high-power ultraviolet light-emitting diodes

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Abstract

The photoinduced grafting polymerization of acrylic acid onto the surface of a polypropylene film under the action of radiation with a wavelength of 365 nm and an intensity of 8–193 mW/cm2 emitted by high-power UV light-emitting diodes is studied. Grafting is performed from a thin layer of the aqueous solution of the monomer onto the surface containing a photoinitiator (benzophenone) deposited from a solution in a volatile solvent. The amount of graft polymer is determined with the use of ATR FTIR spectroscopy. At an intensity of UV radiation of 193 mW/cm2, the time of attainment of grafting-polymerization saturation is decreased by a factor of 6 relative to this time at an intensity of 8 mW/cm2, typical for emitters based on mercury lamps. The rate of grafting polymerization in the studied UV-radiation-intensity range grows in proportion to the square root of intensity.

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Authors and Affiliations

  1. Stepanov Institute of Physics, National Academy of Sciences of Belarus, pr. Nezavisimosti 68, Minsk, 220072, Belarus

    O. N. Tretinnikov, A. A. Gorbachev, E. V. Lutsenko, A. V. Danilchik, L. V. Shkrabatovskaya & L. K. Prikhodchenko

Authors
  1. O. N. Tretinnikov
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  2. A. A. Gorbachev
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  3. E. V. Lutsenko
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  4. A. V. Danilchik
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  5. L. V. Shkrabatovskaya
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  6. L. K. Prikhodchenko
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Corresponding author

Correspondence to O. N. Tretinnikov.

Additional information

Original Russian Text © O.N. Tretinnikov, A.A. Gorbachev, E.V. Lutsenko, A.V. Danilchik, L.V. Shkrabatovskaya, L.K. Prikhodchenko, 2016, published in Vysokomolekulyarnye Soedineniya. Ser. B, 2016, Vol. 58, No. 3, pp. 231–237.

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Tretinnikov, O.N., Gorbachev, A.A., Lutsenko, E.V. et al. Photoinduced grafting polymerization onto the surface with the use of radiation of high-power ultraviolet light-emitting diodes. Polym. Sci. Ser. B 58, 278–283 (2016). https://doi.org/10.1134/S1560090416030155

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  • DOI: https://doi.org/10.1134/S1560090416030155

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