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The well-defined bootstrap effect in the macroinitiator-mediated pseudoliving radical copolymerization of styrene and acrylic acid

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Abstract

The bootstrap effect is observed in the pseudoliving radical copolymerization of styrene and acrylic acid mediated by a macroinitiator: the adduct of poly(acrylic acid) with a nitroxide radical. In this case, the macroinitiator serves as a peculiar “microreactor” with an increased local concentration of acrylic acid; as a result, the apparent activity of acrylic acid is higher than that in copolymerization mediated by low-molecular-mass initiators.

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Authors and Affiliations

  1. Faculty of Chemistry, Moscow State University, Moscow, 119991, Russia

    O. V. Borisova & M. Yu. Zaremski

  2. UPPA, CNRS UMR 5254 IPREM, Equipe de Physique et Chimie des Polyméres, Pau, 2, Avenue du Président Pierre Angot, 64053, Pau Cedex 9, France

    O. V. Borisova, O. V. Borisov & L. Billon

  3. Institute of Macromolecular Compounds, Russian Academy of Sciences, Bol’shoi pr. 31 (V.O.), St. Petersburg, 199004, Russia

    O. V. Borisov

Authors
  1. O. V. Borisova
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  2. M. Yu. Zaremski
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  3. O. V. Borisov
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  4. L. Billon
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Correspondence to O. V. Borisova.

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Original Russian Text © O.V. Borisova, M.Yu. Zaremski, O.V. Borisov, L. Billon, 2013, published in Russian in Vysokomolekulyarnye Soedineniya, Ser. B, 2013, Vol. 55, No. 12, pp. 1486–1489.

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Borisova, O.V., Zaremski, M.Y., Borisov, O.V. et al. The well-defined bootstrap effect in the macroinitiator-mediated pseudoliving radical copolymerization of styrene and acrylic acid. Polym. Sci. Ser. B 55, 573–576 (2013). https://doi.org/10.1134/S1560090413090017

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  • DOI: https://doi.org/10.1134/S1560090413090017

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