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Polymers of diphenylamine-2-carboxylic acid: Synthesis, structure, and properties

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Abstract

Polymers of diphenylamine-2-carboxylic acid are prepared by chemical oxidative polymerization in an aqueous solution of ammonium hydroxide. In accordance with the IR data, during the polymerization of diphenylamine-2-carboxylic acid in a solution of ammonium hydroxide, polymer-chain growth occurs via C-C joining into 2 and 4 positions of phenyl rings with respect to nitrogen. The distinctive feature of the polymer is the absence of quinodiimine units in its structure, even if the oxidizer is in excess. The resulting polymers are amorphous, electroactive, and thermally stable.

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Authors and Affiliations

  1. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Leninskii pr. 29, Moscow, 119991, Russia

    S. Zh. Ozkan, I. S. Eremeev, G. P. Karpacheva, G. N. Bondarenko & G. A. Shandryuk

  2. OJSC Petrov Plastics Institute, Perovskii pr. 35, Moscow, 111024, Russia

    T. N. Prudskova & E. V. Veselova

Authors
  1. S. Zh. Ozkan
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  2. I. S. Eremeev
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  3. G. P. Karpacheva
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  4. T. N. Prudskova
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  5. E. V. Veselova
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  6. G. N. Bondarenko
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  7. G. A. Shandryuk
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Correspondence to S. Zh. Ozkan.

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Original Russian Text © S.Zh. Ozkan, I.S. Eremeev, G.P. Karpacheva, T.N. Prudskova, E.V. Veselova, G.N. Bondarenko, G.A. Shandryuk, 2013, published in Russian in Vysokomolekulyarnye Soedineniya, Ser. B, 2013, Vol. 55, No. 3, pp. 321–329.

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Ozkan, S.Z., Eremeev, I.S., Karpacheva, G.P. et al. Polymers of diphenylamine-2-carboxylic acid: Synthesis, structure, and properties. Polym. Sci. Ser. B 55, 107–115 (2013). https://doi.org/10.1134/S1560090413030032

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  • DOI: https://doi.org/10.1134/S1560090413030032

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