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Synthesis and study of self-organization of organo-inorganic nanostructures based on cationic poly(meth)acrylates and molybdenum disulfide single layers

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Abstract

Poly(meth)acrylates of three types, namely, regular homopolymers containing side-chain tetraalkylammonium ionic groups with alkyl radicals of various lengths (C6 and C16), a copolymer with statistically distributed ionic and long-chain (C18) alkyl groups, and a block copolymer of the same composition in which alkylammonium and alkyl groups are located in separate blocks, are synthesized with the use of controlled radical polymerization processes. The interaction of the polymers with molybdenum disulfide singlelayer dispersions yields self-organized organic-inorganic nanocomposites containing up to 40% polymer. As evidenced by powder X-ray diffraction and high-resolution transmission electron microscopy structural studies of the composites, they possess a crystalline layered structure with interlayer distances depending on the composition and structure of the polymer. Structures with the most regular alternation of organic and inorganic layers are formed in the case of homopolymers. The orientation of their alkylammonium fragments relative to MoS2 layers depends on the length of the alkyl radical and corresponds to their parallel (C6) or perpendicular (C16) arrangement.

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Authors and Affiliations

  1. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, ul. Vavilova 28, Moscow, 117813, Russia

    Yu. A. Kabachii, S. Yu. Kochev, N. D. Lenenko, A. S. Golub, M. Yu. Antipin & P. M. Valetskii

  2. Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, pr. Akademika Lavrent’eva 5, Novosibirsk, 630090, Russia

    V. I. Zaikovskii

Authors
  1. Yu. A. Kabachii
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  2. S. Yu. Kochev
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  3. N. D. Lenenko
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  4. V. I. Zaikovskii
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  5. A. S. Golub
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  6. M. Yu. Antipin
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  7. P. M. Valetskii
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Correspondence to S. Yu. Kochev.

Additional information

Original Russian Text © Yu.A. Kabachii, S.Yu. Kochev, N.D. Lenenko, V.I. Zaikovskii, A. S. Golub, M.Yu. Antipin, P.M. Valetskii, 2013, published in Russian in Vysokomolekulyarnye Soedineniya, Ser. B, 2013, Vol. 55, No. 2, pp. 243–254.

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Kabachii, Y.A., Kochev, S.Y., Lenenko, N.D. et al. Synthesis and study of self-organization of organo-inorganic nanostructures based on cationic poly(meth)acrylates and molybdenum disulfide single layers. Polym. Sci. Ser. B 55, 95–106 (2013). https://doi.org/10.1134/S1560090413020024

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  • DOI: https://doi.org/10.1134/S1560090413020024

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