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The role of azide groups in the reactions of oligodiols with diisocyanates

  • Modification of Polymers
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Abstract

The kinetic features of the dibutyltin dilaurinate-catalyzed and noncatalyzed reactions of 1,6-hexamethylene diisocyanate with azide-containing oligodiols of various structures and molecular masses are studied. The accelerating effect of azide groups on urethane formation, which is determined by the possibility of activation of free hydroxyl groups via complexation with azide-containing fragments of side chains of oligomers, is established.

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Authors and Affiliations

  1. Institute of Problems of Chemical Physics, Russian Academy of Sciences, pr. Akademika Semenova 1, Chernogolovka, Moscow oblast, 142432, Russia

    M. A. Zaverkina, V. P. Lodygina, E. V. Stovbun, E. R. Badamshina & Yu. M. Mikhailov

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  1. M. A. Zaverkina
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  2. V. P. Lodygina
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  3. E. V. Stovbun
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  4. E. R. Badamshina
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  5. Yu. M. Mikhailov
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Correspondence to M. A. Zaverkina.

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Original Russian Text © M.A. Zaverkina, V.P. Lodygina, E.V. Stovbun, E.R. Badamshina, Yu.M. Mikhailov, 2011, published in Russian in Vysokomolekulyarnye Soedineniya, Ser. B, 2011, Vol. 53, No. 9, pp. 1642–1647.

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Zaverkina, M.A., Lodygina, V.P., Stovbun, E.V. et al. The role of azide groups in the reactions of oligodiols with diisocyanates. Polym. Sci. Ser. B 53, 505 (2011). https://doi.org/10.1134/S1560090411090053

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  • DOI: https://doi.org/10.1134/S1560090411090053

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