Skip to main content
SpringerLink
Log in

Copolymerization of 5-vinyltetrazole with N-vinyllactams and properties of the copolymers

  • Polymerization
  • Published:
Polymer Science Series B Aims and scope Submit manuscript

Abstract

Polymer polyelectrolytes soluble in water in the ionized state are obtained by the free-radical copolymerization of 5-vinyltetrazole with N-vinylcaprolactam, N-vinylpiperidone, and N-vinylpyridone. The aqueous solutions of 5-vinyltetrazole-N-vinylcaprolactam copolymers are pH-thermosensitive and can be described by phase diagrams with a lower critical solution temperature.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Yu. E. Kirsh, Poly(N-vinylpyrrolidone) and Other Poly(N-vinylamides) (Nauka, Moscow, 1998) [in Russian].

    Google Scholar 

  2. V. N. Verezhnikov, T. V. Plaksitskaya, and T. N. Poyarkova, Polymer Science, Ser. A 48, 870 (2006) [Vysokomol. Soedin., Ser. A 48, 1482 (2006)].

    Article  Google Scholar 

  3. Shufu-Peng and Chi-Wu, Macromolecules 34, 568 (2001).

    Article  Google Scholar 

  4. Shufu-Peng and Chi-Wu, Macromolecules 34, 6795 (2001).

    Article  Google Scholar 

  5. E. E. Makhaeva, Heikki Tenhu, and A. R. Khokhlov, Macromolecules 35, 1870 (2002).

    Article  CAS  Google Scholar 

  6. I. M. Okhapkin, I. R. Nasimova, E. E. Makhaeva, and A. R. Khokhlov, Macromolecules 36, 8130 (2003).

    Article  CAS  Google Scholar 

  7. V. N. Kizhnyaev and L. I. Vereshchagin, Vinyltetrazoles (Irkutsk. Gos. Univ., Irkutsk, 2003) [in Russian].

    Google Scholar 

  8. V. N. Kizhnyaev, F. A. Pokatilov, and L. I. Vereshchagin, Polymer Science, Ser. C 50, 1 (2008) [Vysokomol. Soedin., Ser. C 50, 1296 (2008)].

    Article  Google Scholar 

  9. V. N. Kizhnyaev and L. I. Vereshchagin, Usp. Khim. 72, 159 (2003).

    Google Scholar 

  10. D. Arnold and D. N. Thatcher, J. Org. Chem. 34, 1141 (1969).

    Article  CAS  Google Scholar 

  11. G. S. Kolesnikov, Synthesis of Vinyl Derivatives of Aromatic and Heterocyclic Compounds (Khimiya, Moscow, 1960) [in Russian].

    Google Scholar 

  12. V. N. Kizhnyaev, F. A. Pokatilov, N. A. Tsypina, et al., Zh. Org. Khim. 38, 1099 (2002).

    Google Scholar 

  13. V. A. Kabanov, V. P. Zubov, and Yu. D. Semchikov, Complex-Radical Polymerization (Khimiya, Moscow, 1987) [in Russian].

    Google Scholar 

  14. Jen-Feng Kuo and Chuh-Yung Chen, J. Appl. Polym. Sci. 26, 1117 (1981).

    Article  CAS  Google Scholar 

  15. V. N. Kizhnyaev, V. A. Kruglova, V. V. Annenkov, and L. I. Vereshchagin, Vysokomol. Soedin., Ser. B 31, 420 (1989).

    CAS  Google Scholar 

  16. V. N. Kizhnyaev, L. V. Adamova, F. A. Pokatilov, et al., Polymer Science, Ser. A 51, 168 (2009) [Vysokomol. Soedin., Ser. A 51, 218 (2009)].

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Irkutsk State University, ul. Karla Marksa 1, Irkutsk, 664003, Russia

    V. N. Kizhnyaev, E. A. Krakhotkina, T. L. Petrova, G. V. Ratovskii, O. V. Tyukalova, F. A. Pokatilov & A. I. Smirnov

Authors
  1. V. N. Kizhnyaev
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. E. A. Krakhotkina
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. T. L. Petrova
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. G. V. Ratovskii
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. O. V. Tyukalova
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. F. A. Pokatilov
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. A. I. Smirnov
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to V. N. Kizhnyaev.

Additional information

Original Russian Text © V.N. Kizhnyaev, E.A. Krakhotkina, T.L. Petrova, G.V. Ratovskii, O.V. Tyukalova, F.A. Pokatilov, A.I. Smirnov, 2010, published in Russian in Vysokomolekulyarnye Soedineniya, Ser. B, 2010, Vol. 52, No. 8, pp. 1523–1529.

This work was supported by the Federal Special-Purpose program “Scientific and Educational Specialists of Innovation Russia” 2009–2013 (contract P2122).

Rights and permissions

Reprints and permissions

About this article

Cite this article

Kizhnyaev, V.N., Krakhotkina, E.A., Petrova, T.L. et al. Copolymerization of 5-vinyltetrazole with N-vinyllactams and properties of the copolymers. Polym. Sci. Ser. B 52, 480–486 (2010). https://doi.org/10.1134/S1560090410070134

Download citation

  • Received:

  • Revised:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1560090410070134

Keywords

Search

Navigation