Abstract
Copolymerization of butadiene and isoprene on the titanium catalyst proceeds on three types of active sites, and this correspond to the standard set of homopolymerization of isoprene. Sites responsible for the preparation of low-molecular-mass fractions of macromolecules are more active in the copolymerization as compared with homopolymerization of butadiene and isoprene. Change in the hydrodynamic regime in the reaction region is accompanied by an increase in the copolymerization rate due to an increase in the over-all concentration of active sites but it does not affect the typical set of growth sites of macromolecules. Distribution curve of active sites with respect to their reactivity is shifted to the high-molecular-mass region with increasing average weight molecular mass with decreasing average number molecular mass when the corresponding molecular-mass distribution becomes broader.
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Original Russian Text © P.A. Taibulatov, V.Z. Mingaleev, V.P. Zakharov, I.A. Ionova, Yu.B. Monakov, 2010, published in Russian in Vysokomolekulyarnye Soedineniya, Ser. B, 2010, Vol. 52, No. 8, pp. 1491–1449.
This work was supported by the Russian Foundation for Basic Research, project no. 08-03-99005, and Federal Special-Purpose program “Scientific and Educational Specialists of Innovation Russia” (contract 02.740.11.0648).
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Taibulatov, P.A., Mingaleev, V.Z., Zakharov, V.P. et al. Kinetic inhomogeneity of copolymerization sites of butadiene and isoprene on titanium catalyst. Polym. Sci. Ser. B 52, 450–458 (2010). https://doi.org/10.1134/S1560090410070092
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DOI: https://doi.org/10.1134/S1560090410070092