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Imprinted polymer particles for iron uptake: Synthesis, characterization and analytical applications

Polymer Science Series B volume 51, Article number: 344 (2009) Cite this article

Abstract

This work reports the preparation of molecularly imprinted polymer particles for selective extraction and determination of iron ions from aqueous media. The polymer particles were synthesized from Fe(NO3)3, morin, 4-vinylpyridine, ethyleneglycoldimethacrylate, and 2,2′-azobisisobutyronitrile and characterized by IR and DSC both prior to and after removing the Fe-morin complex by leaching with HCl. The effect of different parameters, such as pH, adsorption and desorption time, type and minimum amount of eluent for removing the complex from polymer was evaluated and optimized. The proposed method is characterized by the detection limit of 3.1 µg l−1 anddynamic linear range of 25 to 200 µg l−1, with the relative standard deviation less than 8.8%. The method was applied to the recovery and determination of iron ions in a few real samples.

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References

  1. C. Septhum, V. Rattanaphani, and S. Rattanaphani, Suranaree J. Sci. Technol. 14, 91 (2007).

    Google Scholar 

  2. P. Ryan and M.J. Hynes, J. Inorg. Biochem. 102, 127 (2008).

    Article  CAS  Google Scholar 

  3. R. P. Schwarzenbach, B. I. Escher, K. Fernner, et al., Science (Washington, D. C.) 313, 1072 (2006).

    Article  CAS  Google Scholar 

  4. I. A. Katsoyiannis, A. Zikoudi, and S. J. Hug, Desalination 224, 330 (2008).

    Article  CAS  Google Scholar 

  5. Molecular Imprinted Polymer. Man-Made Mimics of Antibodies and Their Application in Analytical Chemistry, Ed. by B. Sellergren (Elsevier, Amsterdam, 2001).

    Google Scholar 

  6. K. Farrington, E. Magner, and F. Regan, Anal. Chim. Acta 566, 60 (2006).

    Article  CAS  Google Scholar 

  7. F. Puoci, C. Garreffa, F. Iemma, et al., Food Chem. 93, 349 (2005).

    Article  CAS  Google Scholar 

  8. E. Caro, R. M. Marce, P. Cormack, et al., J. Chromatogr., B: Biomed. Appl. 813, 137 (2004).

    Article  CAS  Google Scholar 

  9. I. Chianella, S. A. Piletsky, I. E. Tothill, and B. Chem, Biosens. Bioelectron. 18, 119 (2003).

    Article  CAS  Google Scholar 

  10. C. Baggiani, C. Giovannoli, L. Anfossi, and C. Tozzi, J. Chromatogr., A 938, 35 (2001).

    Article  CAS  Google Scholar 

  11. G. Brambilla, M. Fiori, B. Rizzo, et al., J. Chromatogr., B: Biomed. Appl. 759, 27 (2001).

    Article  CAS  Google Scholar 

  12. J. G. Karlsson, L. I. Andersson, and I. Nicholls, Anal. Chim. Acta 435, 57 (2001).

    Article  CAS  Google Scholar 

  13. M. Khajeh, Y. Yamini, E. Ghasemi, et al., Anal. Chim. Acta 581, 208 (2007).

    Article  CAS  Google Scholar 

Download references

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Authors and Affiliations

  1. Department of Chemistry, University of Zabol, P.O. Box 98615-538, Zabol, Iran

    Mostafa Khajeh

  2. Department of Chemistry, Faculty of Sciences, University of Sistan & Balouchestan, Zahedan, Iran

    Massoud Kaykhaii, Hossein Hashemi & Majid Mirmoghaddam

Authors
  1. Mostafa Khajeh
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  2. Massoud Kaykhaii
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  3. Hossein Hashemi
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  4. Majid Mirmoghaddam
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Correspondence to Mostafa Khajeh.

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The text was submitted by the authors in English.

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Khajeh, M., Kaykhaii, M., Hashemi, H. et al. Imprinted polymer particles for iron uptake: Synthesis, characterization and analytical applications. Polym. Sci. Ser. B 51, 344 (2009). https://doi.org/10.1134/S1560090409090048

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  • DOI: https://doi.org/10.1134/S1560090409090048

Keywords

  • Polymer Science Series
  • Morin
  • AIBN
  • Molecular Imprint Polymer
  • Imprint Polymer