Abstract
The binary radical copolymerization of acrylic acid amides (acrylamide and N-cyclohexen-1-ylacrylamide) with alkenyl halides (vinyl chloride, vinyl bromide, and allyl chloride) has been studied. The constants of relative activity of the monomers used are calculated. For the systems under investigation, the occurrence of dehydrochlorination of a polymer chain and protonation of a carbonyl group occur is confirmed. Allyl chloride shows the most pronounced tendency toward dehydrochlorination, while in the case of vinyl chloride, this tendency is the least distinct. The polymer-analogous transformations result in copolymers containing polyene fragments and units of ammonium or oxonium amide salts.
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L. I. Abramova, T. A Baiburdov, E. P. Grigoryan, E. N. Zil’berman, V. F. Kurenkov, and V. A. Myagchenkov, Polyacrylamide (Khimiya, Moscow, 1992) [in Russian].
B. A. Trofimov, O. A. Tarasova, M. V. Sigalov, and A. J. Michaleva, Tetrahedron Lett. 36, 9181 (1995).
T. V. Raskulova, V. A. Komarova, L. V. Kanitskaya, et al., Polymer Science, Ser. B 44, 53 (2002) [Vysokomol. Soedin., Ser. B 44, 496 (2002)].
K. S. Minsker and G. T. Fedoseeva, Degradation and Stabilization of Poly(vinyl chloride) (Khimiya, Moscow, 1979) [in Russian].
I. M. Kolthoff, S. Bruskenstein, and M. K. Chantooni, J. Am. Chem. Soc. 83, 3927 (1961).
A. J. Gordon and R. A. Ford, The Chemist’s Companion (Wiley, New York, 1972).
A. A. Berlin, Vysokomol. Soedin. 8, 1336 (1966).
J. L. Koenig, Spectroscopy of Polymers (ACS Prof. Ref. Book, American Chemical Society, Washington, 1992).
H. O. Kalynowsky, S. Berger, and S. Braun, Carbon-13 NMR Spectroscopy (Wiley, New York, 1988).
T. V. Raskulova and B. A. Shainyan, Zh. Obshch. Khim., No. 7, 647 (2003).
M. Witanowski and G. A. Webb, Nitrogen NMR (Plenum, London, 1973).
K. Nakanishi, Infrared Absorption Spectroscopy (Holden Day, Tokyo, 1962; Mir, Moscow, 1965).
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Original Russian Text © T.V. Raskulova, L.V. Kanitskaya, O.A. Tarasova, G.F. Myachina, A.K. Khaliullin, 2009, published in Vysokomolekulyarnye Soedineniya, Ser. B, 2009, Vol. 51, No. 7, pp. 1218–1243.
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Raskulova, T.V., Kanitskaya, L.V., Tarasova, O.A. et al. Copolymerization of acrylic acid amides with alkenyl halides. Polym. Sci. Ser. B 51, 233–238 (2009). https://doi.org/10.1134/S1560090409070057
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DOI: https://doi.org/10.1134/S1560090409070057