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Copolymerization of diallyl isophthalate with methyl methacrylate and styrene in the presence of C60 fullerene

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Abstract

The involvement of fullerene in the radical copolymerization of diallyl isophthalate with methyl methacrylate or styrene results in a change in the relative activity of monomers owing to the interaction of C60 with the allyl radical yielding a “quo;new,”quo; more active radical. This corresponds to the transition from degradative chain transfer to effective transfer to the allyl compound. It is of great importance that, at an amount of diallyl isophthalate in the monomer mixture of up to 10 mol %, C60 fullerene is almost completely incorporated into macromolecules.

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References

  1. V. I. Volodina, A. I. Tarasov, and S. S. Spasskii, Usp. Khim. 34, 276 (1970).

    Google Scholar 

  2. R. Kh. Yumagulova, Yu. N. Biglova, S. V. Kolesov, and Yu. B. Monakov, Dokl. Akad. Nauk 408, 625 (2006).

    Google Scholar 

  3. R. Kh. Yumagulova, Yu. N. Biglova, S. I. Kuznetsov, et al., Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol. 50(6), 62 (2007).

    CAS  Google Scholar 

  4. R. Kh. Yumagulova, S. V. Kolesov, and V. P. Budtov, Polymer Science, Ser. B 48, 324 (2006) [Vysokomol. Soedin., Ser. B 48, 2186 (2006)].

    Article  Google Scholar 

  5. G. P. Gladyshev, Polymerization of Vinyl Monomers (Akad. Nauk Kaz. SSR, Alma-Ata, 1964) [in Russian].

    Google Scholar 

  6. A. Matsumoto and M. Oiwa, Kogyo Kagaku Zasshi. Jpn. 70, 360 (1967).

    CAS  Google Scholar 

  7. A. Matsumoto, Shoda, Shozo, Harada, Tsunega, M. Oiwa, Kogyo Kagaku Zasshi. Jpn. 70, 1007 (1967).

    CAS  Google Scholar 

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Authors and Affiliations

  1. Institute of Organic Chemistry, Ufa Scientific Center, Russian Academy of Sciences, pr. Oktyabrya 71, Ufa, 450054, Bashkortostan, Russia

    R. Kh. Yumagulova, S. I. Kuznetsov & S. V. Kolesov

Authors
  1. R. Kh. Yumagulova
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  2. S. I. Kuznetsov
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  3. S. V. Kolesov
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Corresponding author

Correspondence to R. Kh. Yumagulova.

Additional information

Original Russian Text © R.Kh. Yumagulova, S.I. Kuznetsov, S.V. Kolesov, 2008, published in Vysokomolekulyarnye Soedineniya, Ser. B, 2008, Vol. 50, No. 7, pp. 1272–1276.

This work was supported by the Russian Foundation for Basic Research (project no. 07-03-00272-a).

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Yumagulova, R.K., Kuznetsov, S.I. & Kolesov, S.V. Copolymerization of diallyl isophthalate with methyl methacrylate and styrene in the presence of C60 fullerene. Polym. Sci. Ser. B 50, 168–171 (2008). https://doi.org/10.1134/S1560090408070026

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  • DOI: https://doi.org/10.1134/S1560090408070026

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