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Nanoporous crosslinked macrocyclic polyethers based on diethylene glycol divinyl ether and their superbase complexes with KOH

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Abstract

Nanoporous (11–12 nm) crosslinked macrocyclic polyethers with vinyloxy and hydroxyl groups have been synthesized by the free-radical polymerization of diethylene glycol divinyl ether (AIBN, 80°C, i-octane), followed by acidic hydrolysis. It has been shown that the polymers react with KOH to form insoluble superbase complexes and alcoholates capable of catalyzing vinylation of ethylene glycol by acetylene.

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Authors and Affiliations

  1. Institute of Organic Chemistry, Siberian Branch, Russian Academy of Sciences, ul. Favorskogo 1, Irkutsk, 664033, Russia

    B. A. Trofimov, L. V. Morozova, A. I. Mikhaleva, I. V. Tatarinova & M. V. Markova

  2. BASF Aktiengesellschaft, Ammoniaklaboratorium ZAR/C, M 311, 67056, Ludwigshafen, Germany

    J. Henkelmann

Authors
  1. B. A. Trofimov
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  2. L. V. Morozova
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  3. A. I. Mikhaleva
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  4. I. V. Tatarinova
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  5. M. V. Markova
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  6. J. Henkelmann
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Corresponding author

Correspondence to L. V. Morozova.

Additional information

Original Russian Text © B.A. Trofimov, L.V. Morozova, A.I. Mikhaleva, I.V. Tatarinova, M.V. Markova, J. Henkelmann, 2008, published in Vysokomolekulyarnye Soedineniya, Ser. B, 2008, Vol. 50, No. 6, pp. 1107–1112.

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Trofimov, B.A., Morozova, L.V., Mikhaleva, A.I. et al. Nanoporous crosslinked macrocyclic polyethers based on diethylene glycol divinyl ether and their superbase complexes with KOH. Polym. Sci. Ser. B 50, 150–154 (2008). https://doi.org/10.1134/S1560090408050114

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  • DOI: https://doi.org/10.1134/S1560090408050114

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