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Copolymerization of N,N-diallyl-N,N-dimethylammonium chloride and vinyl acetate

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Abstract

The free-radical copolymerization of N,N-diallyl-N,N-dimethylammonium chloride with vinyl acetate in DMSO, methanol, and a methanol-water (70: 30, mol %) mixture proceeds to yield statistical copolymers. The nature of solvents significantly affects the reactivity ratios of the comonomers. N,N-Diallyl-N,N-dimethylammonium chloride shows a higher reactivity than vinyl acetate. The kinetic features of the processes have been investigated, and the structure and properties of the copolymers have been studied.

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Authors and Affiliations

  1. Institute of Organic Chemistry, Ufa Scientific Center, Russian Academy of Sciences, pr. Oktyabrya 71, Ufa, 450054, Bashkortostan, Russia

    A. I. Vorob’eva, I. R. Aleev, V. P. Volodina, Yu. A. Prochukhan & Yu. B. Monakov

  2. Ufa State Academy of Economics and Service, ul. Chernyshevskogo 145, Ufa, 450078, Bashkortostan, Russia

    D. R. Sagitova & Yu. B. Monakov

Authors
  1. A. I. Vorob’eva
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  2. D. R. Sagitova
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  3. I. R. Aleev
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  4. V. P. Volodina
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  5. Yu. A. Prochukhan
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  6. Yu. B. Monakov
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Corresponding author

Correspondence to Yu. B. Monakov.

Additional information

Original Russian Text © A.I. Vorob’eva, D.R. Sagitova, I.R. Aleev, V.P. Volodina, Yu.A. Prochukhan, Yu.B. Monakov, 2008, published in Vysokomolekulyarnye Soedineniya, Ser. B, 2008, Vol. 50, No. 6, pp. 1092–1098.

This work was supported by the State Program for Support of Leading Scientific Schools, grant no. NSh-9342.2006.3.

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Vorob’eva, A.I., Sagitova, D.R., Aleev, I.R. et al. Copolymerization of N,N-diallyl-N,N-dimethylammonium chloride and vinyl acetate. Polym. Sci. Ser. B 50, 139–143 (2008). https://doi.org/10.1134/S1560090408050084

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  • DOI: https://doi.org/10.1134/S1560090408050084

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