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Phase diagrams of a hydroxypropyl cellulose-water system under static conditions and in the shear field

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Abstract

Phase diagrams have been constructed for a hydroxypropyl cellulose-water system under static conditions and in a shear field by the cloud-point method and a transmitted polarized light intensity measurements. As the molecular mass of the polymer is increased, the curve delimiting isotropic and anisotropic solutions shifts to lower concentrations. Deformation causes changes in the phase transition temperatures of solutions both upon heating and cooling.

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References

  1. V. G. Kulichikhin and L. K. Golova, Khim. Drev., No. 3, 9 (1985).

  2. D. G. Gray, J. Appl. Polym. Sci., Appl. Polym. Symp. 37, 179 (1983).

    CAS  Google Scholar 

  3. V. P. Belousov and M. Yu. Panov, Thermodynamics of Aqueous Solutions of Nonelectrolytes (Khimiya, Leningrad, 1983) [in Russian].

    Google Scholar 

  4. A. Kagemoto, K. Tada, Y. Baba, and R. Fujishiro, Rep. Prog. Polym. Phys. Jpn. 13, 43 (1970).

    Google Scholar 

  5. B. Nystrom and R. Bergman, Eur. Polym. J. 14, 431 (1978).

    Article  CAS  Google Scholar 

  6. R. S. Werbowyj and D. G. Gray, Macromolecules 13, 69 (1980).

    Article  CAS  Google Scholar 

  7. Y. Nishio, R. Chiba, Y. Miyashita, et al., Polym. J. (Tokyo) 34, 149 (2002).

    CAS  Google Scholar 

  8. S. Fortin and G. Charlet, Macromolecules 22, 2286 (1989).

    Article  CAS  Google Scholar 

  9. R. S. Werbowyj and D. G. Gray, Mol. Cryst. Liq. Cryst. 34, 97 (1976).

    Article  CAS  Google Scholar 

  10. C. Ryotarou and N. Yoshiyuki, Macromolecules 36, 1706 (2003).

    Article  CAS  Google Scholar 

  11. S. Guido, Macromolecules 28, 4530 (1995).

    Article  CAS  Google Scholar 

  12. H. Fisher, M. Murray, A. Keller, and J. A. Odell, J. Mater. Sci. 30, 4623 (1995).

    Article  Google Scholar 

  13. K. Furusawa and T. Tagawa, Colloid Polym. Sci. 263, 353 (1985).

    Article  CAS  Google Scholar 

  14. S. Suto, W. Nishibory, K. Kudo, and M. Karasawa, J. Appl. Polym. Sci. 37, 737 (1989).

    Article  CAS  Google Scholar 

  15. R. S. Werbowyj and D. G. Gray, Polym. Prepr. (Am. Chem. Soc., Div. Polym. Chem.) 20, 102 (1979).

    CAS  Google Scholar 

  16. X. Lu, Z. Hu, and J. Schwartz, Macromolecules 35, 9164 (2002).

    Article  CAS  Google Scholar 

  17. R. Bergman and Z. O. Sundelof, Eur. Polym. J. 13, 881 (1977).

    Article  CAS  Google Scholar 

  18. A. A. Tager, A. P. Safronov, E. A. Berezyuk, and I. Yu. Galaev, Vysokomol. Soedin., Ser. B 32, 572 (1991).

    Google Scholar 

  19. L. D. Taylor and L. D. Cerankowski, J. Polym. Sci., Part A: Polym. Chem. 13, 2551 (1975).

    CAS  Google Scholar 

  20. K. Shimura, J. L. White, and J. F. Feller, J. Appl. Polym. Sci. 26, 2165 (1981).

    Article  Google Scholar 

  21. G. Charlet and D. G. Gray, Macromolecules 20, 33 (1987).

    Article  CAS  Google Scholar 

  22. B. V. Ioffe, Refractometric Methods in Chemistry (Khimiya, Leningrad, 1974) [in Russian].

    Google Scholar 

  23. S. A. Vshivkov and E. V. Rusinova, Mechanically Induced Phase Transitions in Polymer Systems (Ural. Gos. Univ., Yekaterinburg, 2001) [in Russian].

    Google Scholar 

  24. S. P. Papkov and V. G. Kulichikhin, Liquid-Crystalline State of Polymers (Khimiya, Moscow, 1977) [in Russian].

    Google Scholar 

  25. P. J. Flory, Proc. R. Soc. London, A 234, 73 (1956).

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Ural State University, pr. Lenina 51, Yekaterinburg, 620083, Russia

    S. A. Vshivkov & E. V. Rusinova

Authors
  1. S. A. Vshivkov
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  2. E. V. Rusinova
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Correspondence to S. A. Vshivkov.

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Original Russian Text © S.A. Vshivkov, E.V. Rusinova, 2007, published in Vysokomolekulyarnye Soedineniya, Ser. B, 2007, Vol. 49, No. 8, pp. 1591–1595.

This work was supported by the Russian Foundation for Basic Research, project nos. 05-03-32888 and 05-08-17948.

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Vshivkov, S.A., Rusinova, E.V. Phase diagrams of a hydroxypropyl cellulose-water system under static conditions and in the shear field. Polym. Sci. Ser. B 49, 209–212 (2007). https://doi.org/10.1134/S1560090407070093

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  • DOI: https://doi.org/10.1134/S1560090407070093

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