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Synthesis of fluorescent hyperbranched poly(aryl ether ketones) containing biphenyl units

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Abstract

Hyperbranched poly(aryl ether ketones) with M n = (8–10) × 103 and terminal fluorine atoms have been synthesized through the polycondensation of 3,3′,5,5′-tetramethyl-4,4′-dihydroxydiphenyl(A2) and 1,3,5-tris[4-(4-fluorobenzoyl)phenoxy]benzene (B3) taken at a molar ratio of (0.720–0.675): 1. The replacement of the terminal fluorine atoms by residues of m-N,N-dimethylaminophenol yields polymers demonstrating green-blue fluorescence both in solution and in the solid state. Fluorescence quenching is observed at concentrations of the said polymers in solutions above 3 g/l.

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Authors and Affiliations

  1. Alan G. MacDiarmid Laboratory, College of Chemistry, Jilin University, 2699 Qianjin Street, 130012, Changchun, China

    Mu Jianxin, Wu Weichun & Jiang Zhenhua

  2. Mendeleev University of Chemical Technology, Miusskaya pl. 9, Moscow, 125047, Russia

    Mu Jianxin, V. V. Kireev & E. A. Karpuzova

  3. College of Materials Science and Engineering, Jilin University, 125 Renmin Street, 130012, Changchun, China

    Zhang Chunling

Authors
  1. Mu Jianxin
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  2. Zhang Chunling
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  3. Wu Weichun
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  4. Jiang Zhenhua
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  5. V. V. Kireev
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  6. E. A. Karpuzova
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Additional information

Original Russian Text © Mu Jianxin, Zhang Chunling, Wu Weichun, Jiang Zhenhua, V.V. Kireev, E.A. Karpuzova, 2007, published in Vysokomolekulyarnye Soedineniya, Ser. B, 2007, Vol. 49, No. 8, pp. 1585–1590.

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Mu, J., Zhang, C., Wu, W. et al. Synthesis of fluorescent hyperbranched poly(aryl ether ketones) containing biphenyl units. Polym. Sci. Ser. B 49, 203–208 (2007). https://doi.org/10.1134/S1560090407070081

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  • DOI: https://doi.org/10.1134/S1560090407070081

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