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Synthesis and Characterization of Ceramics BaxMg(2 – x)F4 Activated by Tungsten

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Abstract

The possibility of radiation synthesis of luminescent ceramics from a mixture of Ba and Mg fluorides and WO3 oxide is shown for the first time. Synthesis is implemented in a powerful electron beam with an energy of 1.4 MeV by direct exposure of the charge to radiation. It is shown that the characteristic band is observed in the photoluminescence spectrum of the synthesized materials due to the introduction of tungsten, which indicates the incorporation of tungsten into the lattice during radiation synthesis without the use of additional substances in the charge.

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REFERENCES

  1. Atroshchenko, L.V., Burachas, S.F., Gal’chinetskii, L.P., Grinev, B.V., Ryzhikov, V.D., and Starzhinskii, N.G., Kristally, stsintillyatory i detektory ioniziruyushchikh izluchenii na ikh osnove (Crystals, Scintillators and Detectors of Ionizing Radiation Based on Them), Kyiv: Nauk. Dumka, 1998.

  2. Kore, B.P., Kumar, A., Erasmus, L., Kroon, R.E., Terblans, J.J., Dhoble, S.J., and Swart, H.C., Energy transfer mechanisms and optical thermometry of BaMgF4:Yb3+,Er3+ phosphor, Inorg. Chem., 2018, vol. 57, no. 1, pp. 288–299.

    Article  CAS  Google Scholar 

  3. Lisitsyna, L.A. and Lisitsyn, V.M., Composition nanodefects in doped lithium fluoride crystals, Phys. Solid State, 2013, vol. 55, no. 11, pp. 2297–2303.

    Article  CAS  Google Scholar 

  4. Lisitsyn, V.M., Golkovskii, M.G., Lisitsyna, L.A., Dauletbekova, A.K., Musakhanov, D.A., Vaganov, V.A., Tulegenova, A.T., and Karipbayev, Zh.T., MgF2- based luminescing ceramics, Russ. Phys. J., 2019, vol. 61, no. 10, pp. 1908–1913.

    Article  CAS  Google Scholar 

  5. Renfro, G.M., Halliburton, L.E., Sibley, W.A., and Belt, R.F., Radiation effects in LiYF4, J. Phys. C: Solid State Phys., 1980, vol. 13, no. 10, pp. 1941–1950.

    Article  CAS  Google Scholar 

  6. Morato, S.P. and Masedo, T.C.A., F and photochromic centers in LiYF4:Nd crystals, Radiat. Effects, 1983, vol. 72, no. 2, pp. 229–235.

    Article  CAS  Google Scholar 

  7. Wang, M., Mi, C.C., Wang, W.X., Liu, C.H., Wu, Y.F., Xu, Z.R., Mao, C.B., and Xu, S.K., Immunolabeling and NIR-excited fluorescent imaging of hela cells by using NaYF4:Yb,Er upconversion nanoparticles, ACS Nano, 2009, vol. 3, no. 6, pp. 1580–1586.

    Article  CAS  Google Scholar 

  8. Li, Z.Q., Zhang, Y., and Jiang, S., Synthesis of colour tunable lanthanide-ion doped NaYF4 upconversion nanoparticles by controlling temperature, Adv. Mater., 2008, vol. 20, p. 4765.

    Article  CAS  Google Scholar 

  9. Yagi, K., Mori, K., Odawara, O., and Wada, H., Preparation of spherical upconversion nanoparticles NaYF4:Yb,Er by laser ablation in liquid and optical properties, J. Laser Appl., 2020, vol. 32, p. 022062. https://doi.org/10.2351/7.0000089

    Article  CAS  Google Scholar 

  10. Gingl, F., BaMgF4 and Ba2Mg3F10: New examples for structural relationships between hydrides and fluorides, Z. Anorg. Allgem. Chem., 1997, vol. 623, pp. 705–709.

    Article  CAS  Google Scholar 

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Funding

This research was supported by the National Research Tomsk Polytechnic University development program.

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Correspondence to V. M. Lisitsyn.

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Lisitsyn, V.M., Musakhanov, D.A., Korzhneva, T.G. et al. Synthesis and Characterization of Ceramics BaxMg(2 – x)F4 Activated by Tungsten. Glass Phys Chem 49, 288–292 (2023). https://doi.org/10.1134/S1087659623600199

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  • DOI: https://doi.org/10.1134/S1087659623600199

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