Abstract
Thermoplastic elastomers (TPEs) reinforced with detonation nanodiamonds (DNDs) based on styrene-butadiene rubber are developed. The mechanical characteristics of the reinforced compounds with different DND contents are investigated. The developed material shows a 30% increase in compressive strength compared to the unfilled composite and a 10% increase in the tensile strength of the material with the introduction of 0.1% DND.
This is a preview of subscription content, log in via an institution to check access.
REFERENCES
Banerjee, S.S. and Bhowmick, A.K., High-temperature thermoplastic elastomers from rubber–plastic blends: A state-of-the-art review, Rubber Chem. Technol., 2017, vol. 90, pp. 1–36.
Banerjee, S.S. and Bhowmick, A.K., Novel nanostructured polyamide 6/fluoroelastomer thermoplastic elastomeric blends: Influence of interaction and morphology on physical properties, Polymer, 2013, vol. 54, pp. 6561–6571.
Coran, A.Y. and Patel, R., Rubber–thermoplastic compositions. Part IV. Thermoplastic vulcanizates from various rubber–plastic combinations, Rubber Chem. Technol., 1981, vol. 54, pp. 892–903.
Banerjee, S.S., Kumar, K.D., Sikder, A.K., and Bhowmick, A.K., Nanomechanics and origin of rubber elasticity of novel nanostructured thermoplastic elastomeric blends using atomic force microscopy, Macromol. Chem. Phys., 2015, vol. 216, pp. 1666–1674.
Wang, H., Wang, Z., Wang, X., Wang, L., Cai, Y., Hong, K., Sun, L., Lu, G., Zhao, D., and Li, Z., Styrene–butadiene–styrene copolymer-compatibilized interfacial-modified graphene oxide with mechanical and electrical properties, J. Thermoplast. Compos. Mater., 2017, vol. 30, pp. 1228–1241.
Hofmann, D., Thomann, R., and Mülhaupt, R., Thermoplastic SEBS elastomer nanocomposites reinforced with functionalized graphene dispersions, Macromol. Mater. Eng., 2018, vol. 303, p. 1700324.
Amini, M., Ramazani, S.A.A., Haddadi, S.A., and Kheradmand, A., Mechanical, rheological and oxygen barrier properties of ethylene vinyl acetate/diamond nanocomposites for packaging applications, Diamond Relat. Mater., 2019, vol. 99, p. 107523.
Ivanoska-Dacikj, A., Fabrication methods of carbon-based rubber nanocomposites, in Carbon-Based Nanofillers and Their Rubber Nanocomposites, Amsterdam: Elsevier, 2019, pp. 27–47.
Maitra, U., Prasad, K.E., Ramamurty, U., and Rao, C.N.R., Mechanical properties of nanodiamond reinforced polymer-matrix composites, Solid State Commun., 2009, vol. 149, pp. 1693–1697.
Ullah, M., Kausar, A., Siddiq, M., Subhan, M., and Abid Zia, M., Reinforcing effects of modified nanodiamonds on the physical properties of polymer-based nanocomposites: A review, Polym.-Plast. Technol. Eng., 2015, vol. 54, pp. 861–879.
Ayatollahi, M.R., Alishahi, E., Doagou, R.S., and Shadlou, S., Tribological and mechanical properties of low content nanodiamond/epoxy nanocomposites, Composites, Part B, 2012, vol. 43, pp. 3425–3430.
Mochalin, V.N. and Gogotsi, Y., Nanodiamond–polymer composites, Diamond Relat. Mater., 2015, vol. 58, pp. 161–171.
Kuasar, A., Structure and chemistry of polymer/nanodiamond composites, in Hybrid Polymer Composite Materials: Applications, Duxford: Woodhead, 2017, pp. 1–21.
Shenderova, O.A., in Detonation Nanodiamonds: Science and Applications, Vul, A. and Shenderova, O., Eds., New York: Jenny Stanford, 2014, p. 346.
Kislitsyn, V.D., Mokhireva, K.A., Shadrin, V.V., and Svistkov, A.L., Research and modeling of viscoelastic behavior of elastomeric nanocomposites, Vestn. Perm. Nats. Issled. Politekh. Univ., Mekh., 2021, no. 2, pp. 76–87.
Shvidchenko, A.V., and Eidelman, E.D., Vul’, A.Ya., Kuznetsov, N.M., Stolyarova, D.Yu., Belousov, S.I., and Chvalun, S.N., Colloids of detonation nanodiamond particles for advanced applications, Adv. Colloid Interface Sci., 2019, vol. 268, pp. 64–81.
Bernhardt, E.C., Processing of Thermoplastic Materials, New York: Krieger, 1974.
Timoshenko, M.V., Balabanov, S.V., Sychev, M.M., and Nikiforov, D.I., Thermoplastic elastomer for 3D printing by fused deposition modeling, Polym. Sci., Ser. A, 2021, vol. 63, pp. 652–656.
Dolmatov, V.Yu., Detonation-synthesis nanodiamonds: Synthesis, structure, properties and applications, Russ. Chem. Rev., 2007, vol. 76, pp. 339–360.
Dolmatov, V.Yu., Composition materials based on elastomer and polymer matrices filled with nanodiamonds of detonation synthesis, Nanotechnol. Russ., 2009, vol. 14, pp. 556–575.
Funding
The technology obtained for the production of composite materials was supported as part of a grant from the Russian Science Foundation (project no. 20-73-10171).
The physical and mechanical properties were tested as part of the research project “Chemistry, physics, and biology of the nanostate” (state registration number 0081-2022-0001).
Author information
Authors and Affiliations
Corresponding author
Ethics declarations
CONFLICT OF INTEREST
The authors declare that they have no conflicts of interest.
ADDITIONAL INFORMATION
The article was translated by the authors.
Rights and permissions
About this article
Cite this article
Timoshenko, M.V., Balabanov, S.V., Sychov, M.M. et al. The Effect of the Introduction of Detonation Nanodiamonds on the Physical and Mechanical Characteristics of Thermoplastic Elastomers. Glass Phys Chem 49, 314–318 (2023). https://doi.org/10.1134/S108765962360014X
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S108765962360014X