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Synthesis and Investigation of New Vitreous Materials with Two Magnetic Subsystems (Fe3O4 and MnxOy)

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Abstract

New vitreous composite materials (CMs) with two magnetic subsystems are synthesized by impregnation magnetite-containing matrices from iron-containing nanoporous glasses in aqueous MnCl2 and H2C2O4 solutions and the subsequent formation of manganese oxides MnxOy (x = 1, 2, 3; y = 1, 2, 3, 4) inside the pore space of the matrices as a result of thermolysis of the reaction product of the dopants (MnC2O4). The chemical (elemental) and phase compositions, the valence-coordination state of iron and manganese, and the characteristics of the magnetic state of the synthesized CMs are studied and compared with the characteristics of nanoporous matrices.

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Notes

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ACKNOWLEDGMENTS

The studies were carried out using the equipment of the resource centers of the Science Park of St. Petersburg State University “Physical methods of surface investigation” and “Innovative technologies of composite nanomaterials.”

Funding

This study was carried out as part of a state task of Grebenshchikov Institute of Silicate Chemistry, Russian Academy of Sciences with the support of the RF Ministry of Education and Science (state registration no. 1021050501068-5-1.4.3 (project FFEM-2022-0004)).

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  1. Grebenshchikov Institute of Silicate Chemistry, Russian Academy of Sciences, 199034, St. Petersburg, Russia

    O. A. Pshenko, T. V. Antropova, L. N. Kurilenko, I. G. Polyakova & I. N. Anfimova

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  1. O. A. Pshenko
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  2. T. V. Antropova
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  4. I. G. Polyakova
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  5. I. N. Anfimova
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Correspondence to T. V. Antropova.

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Pshenko, O.A., Antropova, T.V., Kurilenko, L.N. et al. Synthesis and Investigation of New Vitreous Materials with Two Magnetic Subsystems (Fe3O4 and MnxOy). Glass Phys Chem 49, 256–263 (2023). https://doi.org/10.1134/S1087659623600114

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