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Composition, Structure, and Transport Properties of Bismuth Containing Porous Glasses in KNO3 Solutions

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Abstract

Bismuth containing porous glasses (BPGs) were prepared on the basis of high-silica micro- and macroporous glasses and also of microporous glasses thermally treated at 750°C. The chemical composition of the glasses was determined by standard analytical methods and X-ray fluorescence analysis. Energy dispersive X-ray analysis showed that bismuth is predominantly formed at the half-thickness of the membranes. Characterization of the glass morphology was carried out by scanning electron microscopy. Their structural properties (specific surface area, volume porosity, structural resistance coefficient, average pore radius) and electrosurface ones (specific electrical conductivity, transport numbers of ions in the pore channels, electrokinetic potential) were studied in 10−4–10−1 M KNO3 solutions in a neutral pH range. The results were compared with similar properties of PG membranes not modified with bismuth(III) oxide. Porous glasses doped with bismuth oxide were found to restore their electrosurface characteristics in the neutral pH range in the concentration range of KNO3 solutions under study.

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ACKNOWLEDGMENTS

The measurements were performed at the Research Park of St. Petersburg State University (Interdisciplinary Resource Centre for Nanotechnology, Centre for X-ray Diffraction Studies and Center for Chemical Analysis and Materials Research, Center for Studies in Surface Science). The authors are grateful to Mr. Ab van der Linde for kindly providing a computer program for calculation of electrokinetic potential under conditions of EDL overlap. The authors also express their gratitude to the coworkers of the Laboratory of the Physical Chemistry of Glass of ISCh RAS T.G. Kostyreva, L.F. Dikaya, and E.A. Semenova for carrying out the chemical analysis of glass samples.

Funding

This work was supported by the RF Ministry of Science and Higher Education as part of the Institute of Silicate Chemistry, Russian Academy of Sciences state assignment (state registration no. 1021050501068-5-1.4.3 (project no. 0081-2022-0004))) and was partially fulfilled with the financial support of Russian Foundation for Basic Research (project no. 18-03-01206).

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Authors and Affiliations

  1. St. Petersburg State University, 199034, St. Petersburg, Russia

    A. S. Kuznetsova, L. E. Ermakova & A. V. Volkova

  2. Grebenshchikov Institute of Silicate Chemistry, Russian Academy of Sciences, 199034, St. Petersburg, Russia

    A. S. Kuznetsova, M. A. Girsova, I. N. Anfimova, L. N. Kurilenko & T. V. Antropova

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  1. A. S. Kuznetsova
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  2. L. E. Ermakova
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  3. M. A. Girsova
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  4. I. N. Anfimova
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  5. L. N. Kurilenko
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  6. A. V. Volkova
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  7. T. V. Antropova
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Correspondence to A. S. Kuznetsova.

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Kuznetsova, A.S., Ermakova, L.E., Girsova, M.A. et al. Composition, Structure, and Transport Properties of Bismuth Containing Porous Glasses in KNO3 Solutions. Glass Phys Chem 48, 598–613 (2022). https://doi.org/10.1134/S1087659622600375

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  • DOI: https://doi.org/10.1134/S1087659622600375

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