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Prediction of the Liquidus of the Quaternary System of Titanium, Aluminum, Silicon, and Zirconium Oxides

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Abstract

The aim of this article is to predict possible invariant reactions in a quaternary system formed by oxides of titanium, aluminum, silicon, and zirconium. As a result, based on the data on invariant transformations in faceting ternary systems, a scheme of phase reactions with the participation of a liquid is derived, and then the contours of the liquidus hypersurfaces are described for basic invariant points belonging to binary and ternary systems, as well as the six obtained points of the quaternary system: two are peritectic, two are eutectic, and two are intermediate, corresponding to phase reactions of two variants of the peritectic type.

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Funding

This study was carried out with the financial support of the Russian Foundation for Basic Research and the State Atomic Energy Corporation Rosatom as part of scientific project no. 20-21-00056.

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Authors and Affiliations

  1. Institute of Physical Materials Science, Siberian Branch, Russian Academy of Sciences, 670047, Ulan-Ude, Russia

    V. P. Vorob’eva, A. E. Zelenaya & V. I. Lutsyk

  2. Grebenshchikov Institute of Silicate Chemistry, Russian Academy of Sciences, 199034, St. Petersburg, Russia

    V. I. Almjashev, V. A. Vorozhtcov & V. L. Stolyarova

  3. Aleksandrov Scientific and Research Technological Institute, 188540, Sosnovy Bor, Leningrad oblast, Russia

    V. I. Almjashev

  4. St. Petersburg State Electrotechnical University “LETI,”, 197376, St. Petersburg, Russia

    V. I. Almjashev

  5. St. Petersburg State University, 199034, St. Petersburg, Russia

    V. L. Stolyarova

Authors
  1. V. P. Vorob’eva
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  2. A. E. Zelenaya
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  3. V. I. Lutsyk
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  4. V. I. Almjashev
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  5. V. A. Vorozhtcov
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  6. V. L. Stolyarova
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Correspondence to V. P. Vorob’eva.

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Vorob’eva, V.P., Zelenaya, A.E., Lutsyk, V.I. et al. Prediction of the Liquidus of the Quaternary System of Titanium, Aluminum, Silicon, and Zirconium Oxides. Glass Phys Chem 47, 616–621 (2021). https://doi.org/10.1134/S1087659621060328

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  • DOI: https://doi.org/10.1134/S1087659621060328

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