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New Composite Materials Based on Nanoporous Glasses Containing Manganese Oxides

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Abstract

A technique is developed and new composite materials containing manganese oxides MnxOy (x = 1, 2, 3; y = 2, 3, 4) are synthesized based on high-silica nanoporous glasses (NPGs). The synthesis is carried out by successive impregnation of porous glass plates in aqueous solutions of manganese chloride (MnCl2) and oxalic acid (H2C2O4), followed by heat treatment of the samples in an argon atmosphere to decompose the reaction product (MnC2O4). The chemical composition and phase composition of the obtained composites are investigated.

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ACKNOWLEDGMENTS

The authors thank I.N. Anfimov for the synthesis of porous glass. They also thank T.G. Kostyrev and L.F. Wild for their help in determining the chemical composition of the research objects.

Funding

Development of a methodology and synthesis of new composite materials containing manganese oxides were carried out as part of project SP-2728.2021.1, supported by a scholarship of the President of the Russian Federation for young scientists and graduate students carrying out promising research and development in priority areas of the modernization of the Russian economy (2021–2023). Part of the study concerning the synthesis of two-phase and porous glasses, as well as the chemical and phase analysis of the synthesized composites, was carried out as part of a state assignment of the Institute of Chemistry of the Russian Academy of Sciences with the support of the Ministry of Education and Science of Russia (topic no. AAAA-A19-119022290087-1).

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Authors and Affiliations

  1. Grebenshchikov Institute of Silicate Chemistry, Russian Academy of Sciences, 199034, St. Petersburg, Russia

    O. A. Pshenko, M. Yu. Arsentiev, L. N. Kurylenko & T. V. Antropova

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  1. O. A. Pshenko
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  2. M. Yu. Arsentiev
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  3. L. N. Kurylenko
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  4. T. V. Antropova
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Correspondence to O. A. Pshenko.

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Pshenko, O.A., Arsentiev, M.Y., Kurylenko, L.N. et al. New Composite Materials Based on Nanoporous Glasses Containing Manganese Oxides. Glass Phys Chem 47, 446–450 (2021). https://doi.org/10.1134/S1087659621050126

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  • DOI: https://doi.org/10.1134/S1087659621050126

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