Skip to main content
SpringerLink
Log in

Production Conditions of Nanoporous Ceramics Based on Mullite

  • Published:
Glass Physics and Chemistry Aims and scope Submit manuscript

Abstract

A technology for producing nanoporous ceramics based on mullite (3Al2O3 ⋅ 2SiO2) is developed. The mechanochemical activation of oxides involved in the synthesis of mullite (γ-Al2O3 and amorphous SiO2) makes it possible to obtain single-phase 3Al2O3 ⋅ 2SiO2 and to reduce its sintering temperature to 1300°С. The effect of the pressing pressure and the amount of pore-forming additive (ammonium carbonate) on the value of open porosity, pore volume, and pore size distribution in sintered ceramics 3Al2O3 ⋅ 2SiO2 is established. Mullite nanoceramics with open porosity of 42–47%, pore size <200 nm, and compressive strength 50–65 MPa is obtained.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1.
Fig. 2.
Fig. 3.
Fig. 4.
Fig. 5.
Fig. 6.

Similar content being viewed by others

REFERENCES

  1. Komolikov, Yu.I. and Blaginina, L.L., Ceramic micro- and ultrafiltration membrane technology (review), Ogneupory Tekh. Keram., 2002, no. 5, pp. 20–28.

  2. Buyakova, S.P. and Kul’kov, S.N., Formation of the structure of porous ceramics sintered from nanocrystalline powders, Ogneupory Tekh. Keram., 2005, no. 11, pp. 6–11.

  3. Krasnyi, B.L., Tarasovskii, V.P., Krasnyi, A.B., and Kuteinikova, A.L., Properties of porous permeable ceramics based on monofractional corundum powders and nanodispersed binder, Steklo Keram., 2009, no. 6, pp. 18–21.

  4. Morozova, L.V., Kalinina, M.V., and Shilova, O.A., Preparation and properties of porous ceramics based on alumomagnesium spinel and zirconium dioxide, Persp. Mater., 2017, no. 3, pp. 59–69.

  5. Vasil’eva, E.A., Morozova, L.V., Lapshin, A.E., and Konakov, V.G., A porous ceramic based on aluminomagnesium spinel, Russ. J. Appl. Chem., 2002, vol. 75, no. 6, pp. 878–882.

    Article  Google Scholar 

  6. Zyryanov, V.V., Multilayer ceramic permselective membranes, Konstrukts. Kompoz. Mater., 2007, no. 1, pp. 32–49.

  7. Vityaz’, P.A., Prokhorov, O.A., Shelekhina, V.M., and Pilinevich, L.P., Ceramic membrane filters: Manufacturing of micro/nanoporous membrane elements, Vestn. DGTU, 2008, vol. 8, no. 1, pp. 37–41.

    Google Scholar 

  8. Matrenin, S.V. and Slosman, A.I., Tekhnicheskaya keramika: Uchebnoe posobie (Technical Ceramics, The School-Book), Tomsk: TPU, 2004.

  9. Dyatlova, E.M., Kakoshko, E.S., and Podbolotov, K.B., Type of raw material and process for activating additives on sintering properties and structure ceramics based Al2O3–SiO2, Ogneupory Tekh. Keram., 2013, no. 7, pp. 12–18.

  10. Strelov, K.K., Teoreticheskie osnovy tekhnologii ogneupornykh materialov: Uchebnoe posobie (Theoretical Principles of Refractory Materials Technology), Moscow: Metallurgiya, 1985.

  11. Vladimirov, V.S., Moizis, S.E., Karpukhin, I.A., Korsun, S.D., and Dolgov, V.I., Porous refractory mullite material and method for its production, RF Patent no. 2182569, Byull., 2002, no. 12.

  12. Gusev, A.I. and Rempel’, A.A., Nanokristallicheskie materialy (Nanocrystalline Materials), Moscow: Fizmatlit, 2001.

  13. Zyryanov, V.V., Mechanochemical ceramic technology, in Mekhanokhimicheskii sintez v neorganicheskoi khimii (Mechanochemical Synthesis in Inorganic Chemistry), Novosibirsk: Nauka, 1991.

  14. Karagedov, G.R. and Lyubushko, G.I., Mechanochemically stimulated synthesis of single-phase mullite, Khim. Inter. Ustoich. Razvit., 1998, vol. 6, nos. 2–3, pp. 161–163.

    CAS  Google Scholar 

  15. Temuujin, J. and Mackenzie, K.D., Comparative study of mechanochemical preparation of aluminosilicate precursors and amorphous silica, Brit. Ceram. Trans., 2000, vol. 99, no. 1, p. 76–79.

    Google Scholar 

  16. Avvakumov, E.G., Lepezin, G.G., and Seretkin, Yu.V., Method of obtaining mullite, RF Patent no. 2463275, Byull., 2012, no. 2.

  17. Pimkov, Yu.V., Filatova, N.V., Kosenko, N.F., and Bezrukov, R.M., Physicochemical analysis of mechanically activated mullitization process, Ogneupory Tekh. Keram., 2014, nos. 4–5, pp. 22–31.

  18. Gusev, A.I. and Kurlov, A.S., Characterization of nanocrystalline materials by the size of particles (grains), Metallofiz. Noveishie Tekhnol., 2008, vol. 30, no. 5, pp. 679–694.

    CAS  Google Scholar 

  19. GOST (Interstate Standard) No. 2409-2014.

  20. GOST (RF National Standard) No. R 7875-83.

  21. GOST (Interstate Standard) Nos. 473.1–81, 473.2–81.

  22. Nazarova, T.I., Ignatova, T.S., Perepelitsyn, V.A, and Kudryavtseva, T.N., The effect of microstructure on the properties of synthetic aluminosilicate products, Ogneupory, 1981, no. 12, pp. 44–47.

  23. Guzman, I.Ya., Vysokoogneupornaya poristaya keramika (Highly Refractory Porous Ceramics), Moscow: Metallurgiya, 1971.

  24. Belyakov, A.V., Solid solutions of silicon oxide in mullite, Steklo Keram., 2003, no. 12, pp. 17–20.

  25. Morozova, L.V., Lapshin, A.E., and Drozdova, I.A., Preparation and investigation of porous aluminosilicate ceramic materials, Glass Phys. Chem., 2008, vol. 34, no. 4, pp. 443–448.

    Article  CAS  Google Scholar 

Download references

ACKNOWLEDGMENTS

The author thanks Doctor of Chemistry A.E. Lapshin for the X-ray phase analysis and Candidate of Chemical Sciences E.A. Vasil’eva for her help in discussing the mercury porosimetry data.

Funding

The work was carried out as part of the research project “Inorganic synthesis and research of ceramic and organoinorganic composite materials and coatings.”

State registration number (CIT and C): АААА-А19-119022290091-8.

Author information

Authors and Affiliations

  1. Grebenshchikov Institute of Silicate Chemistry, Russian Academy of Sciences, 199034, St. Petersburg, Russia

    L. V. Morozova

Authors
  1. L. V. Morozova
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to L. V. Morozova.

Ethics declarations

The authors declare to have no conflict of interest.

Additional information

Translated by Sh. Galyaltdinov

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Morozova, L.V. Production Conditions of Nanoporous Ceramics Based on Mullite. Glass Phys Chem 46, 570–575 (2020). https://doi.org/10.1134/S1087659620060152

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1087659620060152

Keywords:

Search

Navigation