Skip to main content
Log in

Exploration of Nonlinear Optical Features of Ga2S3–La2S3 Glasses for Optoelectronic Applications

  • Published:
Glass Physics and Chemistry Aims and scope Submit manuscript

Abstract—

An opportunity to operate by laser-induced nonlinear optical efficiencies of Ga2S3–La2S3 glasses doped with Er3+ and La3+ ions in the visible and near-infrared spectral ranges was explored. The laser-stimulated nonlinear optical properties were studied. The observed laser power and temperature dependences of the laser-stimulated second-harmonic generation and third-harmonic generation confirm the huge role of anharmonic phonon subsystems. Due to an occurrence of local structural distortions, the efficiency of laser nonlinear optical generation has been enhanced. Simultaneous occurrence of the second and third-order nonlinear optical response may indicate on the possibility of multifunctional applications of the investigated glasses in different electronic devices.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1.
Fig. 2.
Fig. 3.
Fig. 4.
Fig. 5.

Similar content being viewed by others

REFERENCES

  1. Mid-Infrared Coherent Sources and Applications, Ebrahim-Zadeh, M. and Sorokina I.T., Eds., Barcelona, Spain: Springer, 2008.

  2. Sanghera, J.S., Shaw, L.B., and Aggarwal, I.D., Chalcogenide glass-fiber-based mid-IR sources and applications, IEEE J. Sel. Top. Quantum Electron., 2009, vol. 15, no. 1, pp. 114–119.

    Article  CAS  Google Scholar 

  3. Halyan, V.V., Kityk, I.V., Kevshyn, A.H., Ivashchenko, I.A., Lakshminarayana, G., Shevchuk, M.V., Fedorchuk, A., and Piasecki, M., Effect of temperature on the structure and luminescence properties of Ag0.05Ga0.05Ge0.95S2–Er2S3 glasses, J. Lumin., 2017, vol. 181, pp. 315–320.

    Article  CAS  Google Scholar 

  4. Halyan, V.V., Khyzhun, O.Y., Ivashchenko, I.A., Kevshyn, A.H., Olekseyuk, I.D., Tyshchenko, P., Vovk, O.P., and Bulik, Y.V., Electronic structure and optical properties of (Ga70La30)2S300 and (Ga69.75La29.75Er0.5)2S300 single crystals, novel light-converting materials, Phys. B (Amsterdam, Neth.), 2018, vol. 544, pp. 10–16.

    Google Scholar 

  5. Sabapathy, T., Ayiriveetil, A., Kar, A.K., Asokan, S., and Beecher, S.J., Direct ultrafast laser written C-band waveguide amplifier in Er-doped chalcogenide glass, Opt. Mater. Express, 2012, vol. 2, pp. 1556–1561.

    Article  CAS  Google Scholar 

  6. Désévédavy, F., Renversez, G., Troles, J., Houizot, P., Brilland, L., Vasilief, I., Coulombier, Q., Traynor, N., Smektala, F., and Adam, J.-L., Chalcogenide glass hollow core photonic crystal fibers, Opt. Mater., 2010, vol. 32, no. 11, pp. 1532–1539.

    Article  Google Scholar 

  7. Mairaj, A.K., Optical waveguide and lasers in improved gallium lanthanum sulphide glass, PhD Thesis, Southampton, UK: Univ. of Southampton, 2003.

  8. Schweizer, T., Hewak, D.W., Payne, D.N., Jensen, T., and Huber, G., Rare earth doped chalcogenide glass laser, Electron. Lett., 1996, vol. 32, no. 7, pp. 666–667.

    Article  CAS  Google Scholar 

  9. Schweizer, T., Samson, B.N., Moore, R.C., Hewak, D.W., and Payne, D.N., Rare-earth doped chalcogenide glass fibre laser, Electron. Lett., 1997, vol. 33, pp. 414–416.

    Article  CAS  Google Scholar 

  10. Tahmasebi, Z. and Hatami, M., Study of the gain saturation effect on the propagation of dark soliton in Er+3-doped, Ga5Ge20Sb10S65 chalcogenide fiber amplifier, Opt. Commun., 2011, vol. 284, no. 2, pp. 656–659.

    Article  CAS  Google Scholar 

  11. Loireau-Lozaćh, A.M., Guittard, M., and Flahaut, J., Verres formes par les sulfures L2S3 des terres rares avec le sulfure de gallium Ga2S3, Mater. Res. Bull., 1976, vol. 11, no. 12, pp. 1489–1496.

    Article  Google Scholar 

  12. Loireau-Lozaćh, A.M., Guittard, M., and Flahaut, J., Systémes L2S3–Ga2S3 (L = La, Ce, Dy, Er et Y) diagrammes de phases, Mater. Res. Bull., 1977, vol. 12, no. 9, pp. 881–886.

    Article  Google Scholar 

  13. Chaudhari, C., Liao, M., Suzuki, T., and Ohishi, Y., Chalcogenide core tellurite cladding composite microstructured fiber for nonlinear applications, J. Lightwave Technol., 2012, vol. 30, no. 13, pp. 2069–2076.

    Article  CAS  Google Scholar 

  14. Majchrowski, A., Chrunik, M., Kityk, I.V., Ozga, K., Michalski, E., Morawiak, P., and Jaroszewicz, L.R., Photoinduced optical effects in rare earth doped δ‑BiB3O6, Mater. Lett., 2014, vol. 122, pp. 114–116.

    Article  CAS  Google Scholar 

  15. Kityk, I.V. and Majchrowski, A., Second-order non-linear optical effects in BiB3O6 glass fibers, Opt. Mater., 2004, vol. 25, pp. 33–37.

    Article  CAS  Google Scholar 

  16. Slyvka, Y.I., Fedorchuk, A.A., Pokhodylo, N.T., Lis, T., Kityk, I.V., and Mys’kiv, M.G., A novel copper(I) sulfamate pi-complex based on the 5-(allylthio)-1-(3,5-dimethylphenyl)-1H-tetrazole ligand: Alternating-current electrochemical crystallization, DFT calculations, structural and NLO properties studies, Polyhedron, 2018, vol. 147, pp. 86–93.

    Article  CAS  Google Scholar 

  17. Driscoll, T.J. and Lawandy, N.M., Optically encoded second-harmonic generation in bulk silica-based glasses, J. Opt. Soc. Am. B, 1994, vol. 11, pp. 355–371.

    Article  CAS  Google Scholar 

  18. Antonyuk, B.P. and Antonyuk, V.B., Self-organization of excitations in Ge-doped silica fibers and its role in second harmonic generation, Phys. Usp., 2001, vol. 44, pp. 53–70.

    Article  CAS  Google Scholar 

  19. Kityk, I.V., Golis, E., Filipecki, J., Wasylak, J., and Zacharko, V.M., Photoinduced nonlinear optical phenomena in PbO–BiO1.5–GaO1.5 glass, J. Mater. Sci. Lett., 1995, vol. 14, pp. 1292–1293.

    Article  CAS  Google Scholar 

  20. Golis, E., Kityk, I.V., Wasylak, J., and Kasperczyk, J., Nonlinear optical properties of lead-bismuth-gallium glasses, Mater. Res. Bull., 1996, vol. 31, no. 9, pp. 1057–1065.

    Article  CAS  Google Scholar 

  21. Myronchuk, G.L., Zamurueva, O.V., Parasyuk, O.V., Piskach, L.V., Fedorchuk, A.O., AlZayed, N.S., El-Naggar, A.M., Ebothe, J., Lis, M., and Kityk, I.V., Structural and optical properties of novel optoelectronic Tl1 – xIn1 – xSixSe2 single crystals, J. Mater. Sci.: Mater. Electron., 2014, vol. 25, pp. 3226–3232.

    CAS  Google Scholar 

Download references

Funding

The authors are grateful to the Deanship of Scientific Research, King Saud University for funding through Vice Deanship of Scientific Research Chairs. The author (A. Dahshan) gratefully thank the Deanship of Scientific Research at King Khalid University for financial support through research groups program under grant number (R.G.P.2/34/40).

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to A. M. El Naggar.

Ethics declarations

The authors declare that they have no conflict of interest.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

El Naggar, A.M., Albassam, A.A., Lakshminarayana, G. et al. Exploration of Nonlinear Optical Features of Ga2S3–La2S3 Glasses for Optoelectronic Applications. Glass Phys Chem 45, 467–471 (2019). https://doi.org/10.1134/S1087659619060142

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1087659619060142

Keywords:

Navigation