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Regularities of Sol-Gel Processes in the Preparation of Polysilicates

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Abstract

The regularities of sol-gel processes in the preparation of potassium polysilicate based on silica hydrosol (Ludox AS-40) are studied. The potassium hydroxide–silica molar ratio (silicate modulus M = [SiO2]/[Me2O]) is set by introducing potassium hydroxide into the sol. The addition of alkali at the initial stage induces sol coagulation. The mechanism of alkali effect is considered taking into account the reactivity of silica (the polycondensation and depolymerization reactions) and the aggregative stability of the colloidal system.

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References

  1. Shabanova, N.A. and Sarkisov, P.D., Osnovy zol’-gel’ tekhnologii nanodispersnogo kremnezema (The Principles of Sol-Gel Technology of Nanodispersed Silica), Moscow: Akademkniga, 2004.

    Google Scholar 

  2. Shabanova, N.A., Popov, V.V., and Sarkisov, P.D., Khimiya i tekhnologiya nanodispersnykh oksidov: Uchebnoe posobie (Chemistry and Technology of Nanodispersed Oxides, The School-Book), Moscow: Akademkniga, 2006.

    Google Scholar 

  3. Shabanova, N.A. and Sarkisov, P.D., Zol’-gel' tekhnologii. Nanodispersnyi kremnezem (Sol-Gel Technologies. Nanodispersed Silica), Moscow: BINOM. Laboratoriya znanii, 2012.

    Google Scholar 

  4. Rakhimov, V.I., Rakhimova, O.V., and Semov, M.P., Aging of As-prepared gels based on tetraethoxysilane in the presence of boric acid, Glass Phys. Chem., 2011, vol. 37, no. 2, pp. 126–134.

    Article  Google Scholar 

  5. Petrova, I.V. and Shilova, O.A., Study of rheological properties of sol–gel systems based on tetraethoxysilanes in the presence of boric acid, gadolinium nitrate, and organic polyols, Glass Phys. Chem., 2016, vol. 42, no. 1, pp. 50–58.

    Article  Google Scholar 

  6. Kokunešoski, M., Šaponjić, A., Stanković, M., Majstorović, J., Egelja, A., Ilić, S., and Matović, B., Development of adiabatic foam using sodium silicate modified by boric acid, J. Alloys Compd., 2016, vol. 666, no. 5, pp. 513–519.

    Google Scholar 

  7. Kokunešoski, M., Šaponjić, A., Stanković, M., Majstorović, J., Egelja, A., Ilić, S., and Matović, B., Effect of boric acid on the porosity of clay and diatomite monoliths, Ceram. Int., 2016, vol. 42, no. 5, pp. 6383–6390.

    Google Scholar 

  8. Ye, Li., Cheng, X., Cao, W., Gong, L., Zhang, R., and Zhang, H., Development of adiabatic foam using sodium silicate modified by boric acid, J. Alloys Compd., 2016, vol. 666, no. 5, pp. 513–519.

    Google Scholar 

  9. Prentice, L.H., Tyas, M.J., and Burrow, M.F., The effects of boric acid and phosphoric acid on the compressive strength of glass-ionomercements, Dental Mater., 2006, vol. 22, no. 1, pp. 94–97.

    Article  Google Scholar 

  10. Palanti, S., Feci, E., Predieri, G., and Vignali, F., A wood treatment based on siloxanes and boric acid against fungal decay and coleopterhylotrupesbajulus, Int. Biodeteriorat. Biodegradat., 2012, vol. 75, pp. 49–54.

    Article  Google Scholar 

  11. Julbe, A., Larbot, A., Guizard, C., Cot, L., Charpin, J., and Bergez, P., Effect of boric acid addition in colloidal sol-gel derived SiC precursors, Mater. Res. Bull., 1990, vol. 25, no. 5, pp. 601–609.

    Article  Google Scholar 

  12. Bogdanov, S.P., Influence of boron impurities on the crystal structure of cubic boron nitride, Glass Phys. Chem., 2008, vol. 34, no. 2, pp. 218–223.

    Article  Google Scholar 

  13. Shabanova, N.A., Method for production of potassium polysilicates, RF Patent No. 218/2170213 (2001).

    Google Scholar 

  14. Sears, G.W., Jr., Determination of specific surface area of colloidal silica by titration with sodium hydroxide, Anal. Chem., 1956, vol. 28, no. 12, pp. 1981–1983.

    Article  Google Scholar 

  15. Shabanova, N.A., Korneeva, T.V., and Frolov, Yu.G., Structure formation in silicic acid sols, Tr. MKhTI, 1979, no. 107, pp. 71–76.

    Google Scholar 

  16. Frolov, Yu.G., Shabanova, N.A., and Savochkina, T.V., Kinetics of formation and spontaneous dispersion of silicic acid gel, Kolloidn. Zh., 1980, vol. 42, no. 5, pp. 1015–1018.

    Google Scholar 

  17. Alexander, G.B., The reaction of molecular weight silicic acids with molybdic acid, J. Am. Chem. Soc., 1953, vol. 75, no. 22, pp. 5655–5657.

    Article  Google Scholar 

  18. Shabanova, N.A. and Markelova, M.N., Influence of reactivity of the colloidal silica on the properties of conjugate phases, Glass Phys. Chem., 2016, vol. 42, no. 4, pp. 414–420.

    Article  Google Scholar 

  19. Shabanova, N.A. and Sergeeva, M.N., Regularities of the change in colloid-chemical properties of silica hydrosols in the presence of alkali metal hydroxides, Russ. J. Appl. Chem., 2009, vol. 82, no. 5, pp. 832–835.

    Article  Google Scholar 

  20. Sorbenty na osnove silikagelya v radiokhimii (Sorbents Based on Silicagel in Radiochemistry), Laskorin, B.N., Ed., Moscow: Atomizdat, 1977.

  21. Shabanova, N.A. and Sergeeva, M.N., Regularities of the change in colloid-chemical properties of silica hydrosols in the presence of alkali metal hydroxides, Russ. J. Appl. Chem., 2009, vol. 82, no. 5, pp. 832–835.

    Article  Google Scholar 

  22. Ashley, K.D. and Inns, W.B., Control of physical structure of silica-alumina catalyst, Ind. Eng. Chem., 1952, vol. 44, no. 12, pp. 2857–2863.

    Article  Google Scholar 

  23. Silos, I.V., Golubeva, E.V., Konovalov, E.A., and Zakharov, A.P., Regularities of the influence of mineral acids on the kinetics of gelling in colloidal silica, Kolloidn. Zh., 1993, vol. 55, no. 2, pp. 145–151.

    Google Scholar 

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Correspondence to N. A. Shabanova.

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Original Russian Text © N.A. Shabanova, A.Yu. Kolosov, 2018, published in Fizika i Khimiya Stekla.

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Shabanova, N.A., Kolosov, A.Y. Regularities of Sol-Gel Processes in the Preparation of Polysilicates. Glass Phys Chem 44, 199–203 (2018). https://doi.org/10.1134/S1087659618030136

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