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Glass Physics and Chemistry

, Volume 44, Issue 2, pp 71–77 | Cite as

Structure of Ca–Sr–Ba Sodium–Borosilicate Glasses according to 11B and 29Si NMR Spectroscopy

  • A. A. Osipov
  • V. E. Eremyashev
  • L. M. Osipova
Article
  • 32 Downloads

Abstract

The structure of borosilicate glasses is studied with 11B and 29Si NMR spectroscopy in order to investigate the influence of replacement of Na2O by oxides of alkali earth metals on their local structure. The quantitative data are analyzed with respect to their correspondence to the criterion of the average charge of the structural unit. The reasons for the deviation between the experimental results and this criterion are considered. It is shown that, in the case of glass devoid of borate structural units with nonbridging oxygen atoms, the corrected contents of these units are consistent with the predictions of thermodynamic modeling of the structure and properties of oxide glasses.

Keywords

borosilicate glasses NMR spectroscopy structure 

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References

  1. 1.
    Yun, Y.H. and Bray, P.J., Nuclear magnetic resonance studies of the glasses in the system Na2O–B2O3–SiO2, J. Non-Cryst. Solids, 1978, vol. 27, pp. 363–380.CrossRefGoogle Scholar
  2. 2.
    Yun, Y.H., Feller, S.A., and Bray, P.J., Correction and addendum to “Nuclear magnetic resonance studies of the glasses in the system Na2O–B2O3–SiO2,” J. Non-Cryst. Solids, 1979, vol. 33, pp. 273–277.CrossRefGoogle Scholar
  3. 3.
    Dell, W.J., Bray, P.J., and Xiao, S.Z., 11B NMR studies and structural modeling of Na2O–B2O3–SiO2 glasses of high soda content, J. Non-Cryst. Solids, 1983, vol. 58, pp. 1–16.CrossRefGoogle Scholar
  4. 4.
    Manara, D., Grandjean, A., and Neuville, D.R., Structure of borosilicate glasses and melts: A revision of the Yun, Bray and Dell model, J. Non-Cryst. Solids, 2009, vol. 355, pp. 2528–2531.CrossRefGoogle Scholar
  5. 5.
    Manara, D., Grandjean, A., and Neuville, D.R., Advances in understanding the structure of borosilicate glasses: Raman spectroscopy study, J. Am. Mineral., 2009, vol. 94, pp. 777–784.CrossRefGoogle Scholar
  6. 6.
    Vedishcheva, N.M., Shakhmatkin, B.A., and Wright, A.C., Thermodynamic modeling of the structure of sodium borosilicate glasses, Phys. Chem. Glasses, 2003, vol. 44, no. 3, pp. 191–196.Google Scholar
  7. 7.
    Vedishcheva, N.M., Shakhmatkin, B.A., and Wright, A.C., The structure of sodium borosilicate glasses: Thermodynamic modeling vs. experiment, J. Non-Cryst. Solids, 2004, vol. 345–346, pp. 39–44.CrossRefGoogle Scholar
  8. 8.
    Vedishcheva, N.M., Shakhmatkin, B.A., and Wright, A.C., Thermodynamic modeling of the structure and properties of glasses in the systems Na2O–B2O3–SiO2 and Na2O–CaO–SiO2, Phys. Chem. Glasses, 2004, vol. 46, no. 2, pp. 99–107.Google Scholar
  9. 9.
    Vedishcheva, N.M., Polyakova, I.G., and Wright, A.C., Short and intermediate range order in sodium borosilicate glasses: A quantitative thermodynamic approach, Phys. Chem. Glasses: Eur. J. Glass Sci. Technol., Part B, 2014, vol. 55, no. 6, pp. 225–236.Google Scholar
  10. 10.
    Eremyashev, V.E., Osipov, A.A., and Osipova, L.M., Borosilicate glass structure with rare-earth-metal cations substituted for sodium cations, Glass Ceram., 2011, vol. 68, nos. 7–8, pp. 205–208.CrossRefGoogle Scholar
  11. 11.
    Mishra, R.K., Sudarsan, V., Tyagi, A.K., Kaushik, C.P., Raj, K., and Kulshreshtha, S.K., Structural studies of ThO2 containing barium borosilicate glasses, J. Non-Cryst. Solids, 2006, vol. 352, pp. 2952–2957.CrossRefGoogle Scholar
  12. 12.
    Ramkumar, J., Chandramouleeswaran, S., Sudarsan, V., Mishra, R.K., Kaushik, C.P., Raj, K., and Tyagi, A.K., Barium borosilicate glass as a matrix for the uptake dyes, J. Hazard. Mater., 2009, vol. 172, pp. 457–464.CrossRefGoogle Scholar
  13. 13.
    Angeli, F., Villain, O., Schuller, S., Charpentier, T., de Lingy, D., Bressel, L., and Wondraczek, L., Effect of temperature and thermal history on borosilicate glass structure, Phys. Rev. B, 2012, vol. 85, pp. 054110-1–054110-15.CrossRefGoogle Scholar
  14. 14.
    Smedskjaer, M.M., Mauro, J.C., Youngman, R.E., Hogue, C.L., Potuzak, M., and Yue, Y., Topological principles of borosilicate glass chemistry, J. Phys. Chem. B, 2011, vol. 115, pp. 12930–12946.CrossRefGoogle Scholar
  15. 15.
    Martens, R. and Muller-Warmuth, W., Structural groups and their mixing in borosilicate glasses of various compositions—an NMR study, J. Non-Cryst. Solids, 2000, vol. 265, pp. 167–175.CrossRefGoogle Scholar
  16. 16.
    Grandjean, A., Malki, M., Montouillout, V., Debruycker, F., and Massiot, D., Electrical conductivity and 11B NMR studies of sodium borosilicate glasses, J. Non-Cryst. Solids, 2008, vol. 354, pp. 1664–1670.CrossRefGoogle Scholar
  17. 17.
    Fleet, M.E. and Muthupari, S., Coordination of boron in alkali borosilicate glasses using XANES, J. Non-Cryst. Solids, 1999, vol. 255, pp. 233–241.CrossRefGoogle Scholar
  18. 18.
    Nanba, T., Nishimura, M., and Miura, Y., A theoretical interpretation of the chemical shift of 29Si NMR peaks in alkali borosilicate glasses, Geochim. Cosmochim. Acta, 2004, vol. 68, no. 24, pp. 5103–5111.CrossRefGoogle Scholar
  19. 19.
    Feller, S., Mullenbach, T., Franke, M., Bista, S., O’Donovan-Zavada, A., Hopkins, K., Starkenberg, D., McCoy, J., Leipply, D., Stansberry, J., Troendle, E., Affatigato, M., Holland, D., Smith, M.E., Kroeker, S., Michaelis, V.K., and Wern, J.E.C., Structure and properties of barium and calcium borosilicate glasses, Phys. Chem. Glasses: Eur. Glass. Sci. Technol., Part B, 2012, vol. 53, no. 5, pp. 210–218.Google Scholar
  20. 20.
    Furukawa, T. and White, W.B., Raman spectroscopic investigation of sodium borosilicate glass structure, J. Mater. Sci., 1981, vol. 16, pp. 2689–2700.CrossRefGoogle Scholar
  21. 21.
    McMillan, P., Structural studies of silicate glasses and melts—application and limitation of Raman spectroscopy, Am. Mineral., 1984, vol. 69, nos. 7–8, pp. 622–644.Google Scholar
  22. 22.
    Mysen, B.O. and Frantz, J.D., Silicate melts at magmatic temperatures: In-situ structure determination to 1651°C and effect temperature and bulk composition on the mixing behavior of structural units, Contrib. Mineral. Petrol., 1994, vol. 117, pp. 1–14.CrossRefGoogle Scholar
  23. 23.
    Robinet, L., Bouquillon, A., and Hartwing, J., Correlations between Raman parameters and elemental composition in lead and lead alkali silicate glasses, J. Raman Spectrosc., 2008, vol. 39, pp. 618–626.CrossRefGoogle Scholar
  24. 24.
    Matson, P.W., Sharma, S.K., and Philpotts, J.A., The structure of high-silica alkali-silicate glasses: A Raman spectroscopic investigation, J. Non-Cryst. Solids, 1983, vol. 58, nos. 2–3, pp. 323–352.CrossRefGoogle Scholar
  25. 25.
    You, J.L., Jiang, G.C., Hou, H.Y., Chen, H., Wu, Y.Q., and Xu, K.D., Quantum chemistry study on superstructure and Raman spectra of binary sodium silicates, J. Raman Spectrosc., 2005, vol. 36, no. 3, pp. 237–249.CrossRefGoogle Scholar
  26. 26.
    Osipov, A.A., Osipova, L.M., and Eremyashev, V.E., Structure of alkali borosilicate glasses and melts according to Raman spectroscopy data, Glass Phys. Chem., 2013, vol. 39, no. 2, pp. 105–112.CrossRefGoogle Scholar
  27. 27.
    Bhasin, G., Bhatnagar, A., Bhowmik, S., Stehle, C., MacKenzie, J., Affatigato, M., Feller, S., and Martin, S., Short range order in sodium borosilicate glasses obtained via deconvolution of 29Si MAS NMR spectra, Phys. Chem. Glasses, 1998, vol. 39, no. 5, pp. 269–274.Google Scholar
  28. 28.
    Barlet, M., Kerrache, A., Delaye, J.-M., and Rountree, C.L., SiO2–Na2O–B2O3 density: A comparison of experiments, simulations, and theory, J. Non-Cryst. Solids, 2013, vol. 382, pp. 32–44.CrossRefGoogle Scholar
  29. 29.
    Soleilhavoup, A., Delaye, J.-M., Angeli, F., Caurant, D., and Charpentier, T., Contribution of first-principles calculations to multinuclear NMR analysis of borosilicate glasses, Magn. Reson. Chem., 2010, vol. 48, pp. S159–S170.CrossRefGoogle Scholar

Copyright information

© Pleiades Publishing, Ltd. 2018

Authors and Affiliations

  • A. A. Osipov
    • 1
  • V. E. Eremyashev
    • 1
    • 2
  • L. M. Osipova
    • 1
  1. 1.Institute of Mineralogy, Ural BranchRussian Academy of SciencesMiassRussia
  2. 2.South Urals State UniversityChelyabinskRussia

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