Glass Physics and Chemistry

, Volume 44, Issue 2, pp 92–99 | Cite as

Analysis of the Parameters of the Mössbauer Spectra and the Spectra of Nuclear Quadrupole Resonance of the Superconducting Ceramic YBa2Cu3O7

  • A. V. Marchenko
  • F. S. Nasredinov
  • V. S. Kiselev
  • P. P. Seregin


The parameters of the Mössbauer spectra on 67Cu(67Zn), 67Ga(67Zn) isotopes, and the data of nuclear quadrupole resonance on an 17O isotope are anlayzed, and the lattice gradient of the electric field for the crystal lattice YBa2Cu3O7 is calculated. It is shown that these parameters correspond to the model when the hole is predominantly in the sublattice of the oxygen chain.


nuclear quadrupole interaction parameters Mössbauer spectroscopy nuclear quadrupole resonance charges of atoms in lattices of high-temperature superconductors 


Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.


  1. 1.
    Seregin, N., Marchenko, A., and Seregin, P., Emission Mössbauer Spectroscopy. Electron Defects and Bose-Condensation in Crystal Lattices of High-Temperature Superconductors, Saarbrücken, Germany: LAP Lambert, 2012.Google Scholar
  2. 2.
    Takigawa, M., Hammel, P.C., Heffner, R.H., Fisk, Z., Ott, K.C., and Thompson, J.D., 17O NMR study of local spin susceptibility in aligned YBa2Cu3O7 powder, Phys. Rev. Lett., 1989, vol. 63, pp. 1865–1868.CrossRefGoogle Scholar
  3. 3.
    Tomeno, I., Machi, T., Tai, K., Koshizuka, N., Kambe, S., Hayashi, A., Ueda, Y., and Yasuoka, H., NMR study of spin dynamics at planar oxygen and copper sites in YBa2Cu3O8, Phys. Rev. B, 1994, vol. 49, pp. 15327–15334.CrossRefGoogle Scholar
  4. 4.
    Shore, J., Yang, S., Haase, J., Schwartz, D., and Oldfield, E., Barium nuclear resonance spectroscopic study of YBa2Cu3O7, Phys. Rev. B, 1992, vol. 46, pp. 595–598.CrossRefGoogle Scholar
  5. 5.
    Lombardi, A., Mali, M., Roos, J., and Brinkmann, D., Hyperfine fields at the Ba site in the antiferromagnet YBa2Cu3O6, Phys. Rev. B, 1996, vol. 53, pp. 14268–14273.CrossRefGoogle Scholar
  6. 6.
    Schwarz, K., Ambrosch-Draxl, C., and Blaha, P., Charge distribution and electric-field gradients in YBa2Cu3O7–x, Phys. Rev. B, 1990, vol. 42, pp. 2051–2061.CrossRefGoogle Scholar
  7. 7.
    Yu, J., Freeman, A.J., Podloucky, R., Herzig, P., and Weinberger, P., Origin of electric-field gradients in high-temperature superconductors: YBa2Cu3O7, Phys. Rev. B, 1991, vol. 43, pp. 532–541.CrossRefGoogle Scholar
  8. 8.
    Singh, D.J., Schwarz, K., and Blaha, P., Electric-field gradients in YBa2Cu3O7: Discrepancy between experimental and local-density-approximation charge distributions, Phys. Rev. B, 1992, vol. 46, pp. 5849–5852.CrossRefGoogle Scholar
  9. 9.
    Ivon, K. and Francois, M., Crystal structure of high-Tc oxides, Zeitschr. Phys. B: Condens. Matter, 1989, vol. 76, pp. 413–444.Google Scholar
  10. 10.
    Francois, M., Junod, A., Yvon, K., Kewat, A., Capponl, J., Strobel, P., Marezio, M., and Fischer, P., A Study of the Cu–O chains in the high T c superconductor YBa2Cu3O7 by high resolution neutron povder diffraction, Solid State Commun., 1988, vol. 66, pp. 1117–1125.CrossRefGoogle Scholar
  11. 11.
    Capponi, J.J., Chaillout, C., Hewat, A.W., Lejay, P., Marezio, M., Nguyen, N., Raveau, B., Soubeyroux, J.L., Tholence, J.L., and Tournier, R., Structure of the 100 K superconductor Ba2YCu3O7 between (5–300) K by neutron powder diffraction, Europhys. Lett., 1987, vol. 3, pp. 1301–1307.CrossRefGoogle Scholar
  12. 12.
    Konstantinovic, J., Parette, G., Djordjevic, Z., and Menelle, A., Structural transformations of the YBa2-Cu3O6.84 crystal lattice in the temperatute interval 9 K to 300 K, Solid State Commun., 1989, vol. 70, pp. 163–166.CrossRefGoogle Scholar
  13. 13.
    Le Page, Y., Siegrist, T., Sunshine, S.A., and Schneemeyer, L.F., Murphy D. W., Zahurak S. M., Waszczak J. V., McKinnon W. R., Tarascon J. M., Hull G. W., and Greene L.H., Structural properties of Ba2YCu3O7 high-T c superconductors, Phys. Rev. B, 1987, vol. 36, pp. 3617–3621.CrossRefGoogle Scholar
  14. 14.
    Bordovskii, G.A., Marchenko, A.V., and Seregin, P.P., Atomic charges in YBa2Cu3O7, YBa2Cu4O8, and Y2Ba4Cu7O15 ceramic samples, Glass Phys. Chem., 2009, vol. 35, no. 6, pp. 643–651.CrossRefGoogle Scholar
  15. 15.
    Bordovskii, G.A., Marchenko, A.V., Nasredinov, F.S., and Seregin, P.P., Charge states of atoms in ceramic superconductors HgBa2Can–1CunO2n+2, Tl2Ba2Can–1-CunO2n + 4 and Bi2Sr2Can–1CunO2n + 4 (n = 1, 2, 3), Glass Phys. Chem., 2010, vol. 36, no. 4, pp. 411–418.CrossRefGoogle Scholar
  16. 16.
    Bordovskii, G.A., Anisimova, N.I., Marchenko, A.V., Rabchanova, T.Yu., Seregin, P.P., and Tomil’tsev, E.A., Hyperfine interactions of copper ions in the structure of high-temperature superconductors, Glass Phys. Chem., 2014, vol. 40, no. 3, pp. 333–340.CrossRefGoogle Scholar
  17. 17.
    Bordovskii, G.A., Marchenko, A.V., Doronin, V.A., Rabchanova, T.Yu., and Seregin, P.P., Electric field gradient tensor in positions of rare-earth metals in RBa2Cu3O7 lattices, Glass Phys. Chem., 2014, vol. 40, no. 4, pp. 436–441.CrossRefGoogle Scholar
  18. 18.
    Bordovskii, G.A., Marchenko, A.V., Nikolaeva, A.V., Seregin, P.P., and Bobokhuzhaev, K.U., Determination of atom charge states in lattices of superconducting metal oxides of copper by 61Cu(61Ni) and 67Cu(67Zn) emission Mössbauer spectroscopy, Glass Phys. Chem., 2015, vol. 41, no. 2, pp. 237–243.CrossRefGoogle Scholar
  19. 19.
    Wells, A.F., Structural Inorganic Chemistry, Oxford: Clarendon, 1984, p. 1120.Google Scholar
  20. 20.
    Wortmann, G., Kolodziejczyk, A., Bergold, M., Stadermann, G., Simmons, C.T., and Kaindl, G., Mössbauer studies of YBa2Cu3O7–x type high-T c superconductors, Hyperfine Interact., 1989, vol. 50, pp. 555–568.CrossRefGoogle Scholar

Copyright information

© Pleiades Publishing, Ltd. 2018

Authors and Affiliations

  • A. V. Marchenko
    • 1
  • F. S. Nasredinov
    • 2
  • V. S. Kiselev
    • 1
  • P. P. Seregin
    • 1
  1. 1.Herzen State Pedagogical University of RussiaSt. PetersburgRussia
  2. 2.Peter the Great St. Petersburg Polytechnic UniversitySt. PetersburgRussia

Personalised recommendations