Skip to main content
Log in

Electrokinetic properties of iron-containing microporous glasses

  • Published:
Glass Physics and Chemistry Aims and scope Submit manuscript

Abstract

The electrokinetic properties of the particles of microporous borosilicate glass powder containing the magnetite phase in its composition on the background of an indifferent electrolyte (NaCl) have been studied. It is found that the modification of two-phase sodium borosilicate glass with iron oxide leads to a shift in the position of the isoelectric point from pH 0.5 for alkali borosilicate (ABS) porous glass (PG) to pH 4.1 ± 0.1 for iron-containing ABS PG. The observed changes in the behavior of modified PG open up new prospects for their practical application.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Liao, M.-H. and Chen, D.-H., Preparation and characterization of a novel magnetic nano-adsorbent, J. Mater. Chem., 2002, vol. 12, pp. 3654–3659.

    Article  Google Scholar 

  2. Chang, Y.-C. and Chen, D.-H., Preparation and adsorption properties of monodisperse chitosan-bound Fe3O4 magnetic nanoparticles for removal of Cu(II) ions, J. Colloid Interface Sci., 2005, vol. 28, no. 2, pp. 446–451.

    Article  Google Scholar 

  3. Hua, M., Zhang, S., Pan, B., Zhang, W., Lv, L., and Zhang, Q., Heavy metal removal from water/wastewater by nanosized metal oxides: A review, J. Hazard. Mater., 2012, vols. 211–212, pp. 317–331.

    Article  Google Scholar 

  4. Podoynitsyn, S.N., Sorokina, O.N., and Kovarski, A.L., High-gradient magnetic separation using ferromagnetic membrane, J. Magn. Magn. Mater., 2016, vol. 397, pp. 51–56.

    Article  Google Scholar 

  5. Rybak, A. and Kaszuwara, W., Magnetic properties of the magnetic hybrid membranes based on various polymer matrices and inorganic fillers, J. Alloys Compd., 2015, vol. 648, pp. 205–214.

    Article  Google Scholar 

  6. Kikukawa, T., Kuraoka, K., Kawabe, K., Yamashita, M., Fukumi, K., Hirao, K., and Yazawa, T., Stabilities and pore size effect of proton-conducting organic–inorganic hybrid membranes prepared through surface modification of porous glasses, J. Membr. Sci., 2005, vol. 259, pp. 161–166.

    Article  Google Scholar 

  7. Pshenko, O.A., Drozdova, I.A., Polyakova, I.G., Rogacki, K., Cizman, A., and Poprawski, R., Rysiakiewicz-Pasek E., Antropova T. V. Ferromagnetici-containing porous glasses, Glass Phys. Chem., 2014, vol. 40, no. 2, pp. 167–172.

    Article  Google Scholar 

  8. Martin, J., Vazquez, M., Hernandez-Velez, M., and Mijangos, C., One-dimensional magnetopolymeric nanostructures with tailored sizes, Nanotecnology, 2008, vol. 19, p. 175304.

    Article  Google Scholar 

  9. Eerenstein, W., Mathur, N.D., and Scott, J.F., Multiferroic and magnetoelectric materials, Nature, 2006, vol. 442, pp. 759–765.

    Article  Google Scholar 

  10. Cheong, S.-W. and Mostovoy, M., Multiferroics: a magnetic twist for ferroelectricity, Nat. Mater., 2007, vol. 6, pp. 13–20.

    Article  Google Scholar 

  11. Akbashev, A.R. and Kaul’, A.R., Structural and chemical aspects of the creation of materials with multiferroic properties, Usp. Khim., 2011, vol. 80, no. 12, pp. 1211–1230.

    Article  Google Scholar 

  12. Cizman, A., Bednarski, W., Antropova, T.V., Pshenko, O., Rysiakiewicz-Pasek, E., Waplak, S.S., and Poprawski, R., Structural, dielectric, thermal and electron magnetic resonance studies of magnetic porous glasses filled with ferroelectrics, Composites, Part B, 2014, vol. 64, pp. 16–23.

    Article  Google Scholar 

  13. Pshenko, O.A., Antropova, T.V., Arsent’ev, M.Yu., and Drozdova, I.A., New vitreous nanocomposites containing phases of Fe3O4 and γ-KNO3, Glass Phys. Chem., 2015, vol. 41, no. 5, pp. 509–514.

    Article  Google Scholar 

  14. Cizman, A., Rogacki, K., Rysiakiewicz-Pasek, E., Antropova, T., Pshenko, O., and Poprawski, R., Magnetic properties of novel magnetic porous glass-based multiferroic nanocomposites, J. Alloys Compd., 2015, vol. 649, pp. 447–452.

    Article  Google Scholar 

  15. Pshenko, O.A., Kostyreva, T.G., Dikaya, L.F., and Antropova, T.V., Chemical resistance of two-phase iron-sodium borosilicate glasses in HCl solutions, Fiz. Khim. Stekla, Pis’ma, 2012, vol. 38, no. 6, pp. 858–860.

    Google Scholar 

  16. Zhdanov, S.P., Porous glasses and their structure, Wiss. Z. Friedrich-Schiller-Univ. Jena: Naturwiss. Reihe, 1987, vol. 6, nos. 5–6, pp. 817–830.

    Google Scholar 

  17. Antropova, T.V., Anfimova, I.N., and Golovina, G.F., Influence of the composition and temperature of heat treatment of porous glasses on their structure and light transmission in the visible spectral range, Glass Phys. Chem., 2009, vol. 35, no. 6, pp. 572–579.

    Article  Google Scholar 

  18. Volkova, A., Ermakova, L., Volkova, M., and Antropova, T.V., Determination of electrokinetic potential of porous glasses by methods of streaming potential, electroosmosis and electrophoresis, Opt. Appl., 2010, vol. 40, no. 2, pp. 341–349.

    Google Scholar 

  19. Ermakova, L.E., Sidorova, M.P., and Bogdanova, N.F., Influence of the structure of boundary layers and the nature of counterions on the position of the isoelectric point of silica surfaces, Colloid J., 2006, vol. 68, no. 4, pp. 411–416.

    Article  Google Scholar 

  20. Volkova, A.V., Vaganov, D.A., Bogdanova, N.F., Antropova, T.V., and Ermakova, L.E., Structural and electrosurface properties of porous glass particles, Colloid J., 2015, vol. 77, no. 3, pp. 267–275.

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to A. V. Volkova.

Additional information

Original Russian Text © A.V. Volkova, L.E. Ermakova, E.A. Kashpurina, O.A. Pshenko, T.V. Antropova, 2016, published in Fizika i Khimiya Stekla.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Volkova, A.V., Ermakova, L.E., Kashpurina, E.A. et al. Electrokinetic properties of iron-containing microporous glasses. Glass Phys Chem 42, 322–324 (2016). https://doi.org/10.1134/S1087659616030172

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1087659616030172

Keywords

Navigation