Abstract
Nanostructured composite materials containing both magnetic (Fe3O4) and ferroelectric (γ-KNO3) phases have been synthesized based on ferromagnetic iron-containing porous silicate glass. The nanocomposite structure has been investigated using the methods of transmission electron microscopy and X-ray diffraction analysis. The composites electrical resistivity in the temperature range 298–490 K has been studied as well.
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Poprawski, R., Rysiakiewicz-Pasek, E., Sieradzki, A., Ciżman, A., and Polańska, J., Ferroelectric phase transitions in KNO3 embedded into porous glasses, J. NonCryst. Solids, 2007, vol. 353, no. 47, pp. 4457–4461.
Sieradzki, A., Komar, J., Rysiakiewicz-Pasek, E., Ciżman, A., and Poprawski, R., Calorimetric investigations of phase transitions in KNO3 embedded into porous glasses, Ferroelectrics, 2010, vol. 402, no. 1, pp. 60–65.
Cizmźan, A., Antropova, T., Anfimova, I., Drozdova, I., Rysiakiewicz-Pasek, E., Radoewska, E.B., and Poprawski, R., Size-driven ferroelectric-paraelectric phase transition in TGS nanocomposites, J. Nanopart. Res., 2013, vol. 15, no. 8, article 1807.
Cizmźan, A., Marciniszyn, T., Rysiakiewicz-Pasek, E., Sieradzki, A., Antropova, T.V., and Poprawski, R., Size effects in KDP-porous glass ferroelectric nanocomposites, Phase Transitions, 2013, vol. 86, no. 9, pp. 910–916.
Akbashev, A.R. and Kaul’, A.R., Structural and chemical aspects of the design of materials with multiferroic properties, Usp. Khim., 2011, vol. 80, no. 12, pp. 1211–1230.
Baryshnikov, S.V., Charnaya, E.V., Milinskii, A.Yu., Shatskaya, Yu.A., and Michel, D., Dielectric and calorimetric investigations of KNO3 in pores of nanoporous silica matrixes MCM-41, Phys. Solid State, 2012, vol. 54, no. 3, pp. 636–642.
Lapshin, A.E., Arsent’ev, M.Yu., Pshenko, O.A., and Antropova, T.V., Structure of the ferroelectric phase KNO3, formed in nanoporous glass matrix, Fiz. Khim. Stekla, 2012, vol. 38, no. 6, pp. 817–819.
Antropova, T., Anfimova, I., Drozdova, I., Polyakova, I., Pshenko, O., Stolyar, S., and Kostyreva, T., Structure of the magnetic phase-separated and nanoporous glasses, in Abstract of the Tenth Seminar “Porous Glasses—Special Glasses (PGL’2011),” Wroclaw, Poland, August 30–September 3, 2011, Wroclaw, 2011, p. 10.
Antropova, T.V., Anfimova, I.N., Pshenko, O.A., Lurie, S.V., Drozdova, I.A., Polyakova, I.G., and Kostyreva, T.G., Nanoporous magnetic matrixes for composites with the properties of multiferroics, in Tezisy dokladov III Mezhdunarodnoi nauchnoi konferentsii “Nanostrukturnye materially—2012: Rossiya-Ukraina-Belarus’ (NANO-2012)” Sankt-Peterburg, 2012 (Abstracts of Papers of the Third International Scientific Conference “Nanostuctured Materials—2012: Russia-Ukraine-Belarus (NANO-2012),” St. Petersburg, Russia, November 19–22, 2012), St. Petersburg, 2012, p. 169.
Antropova, T.V., Anfimova, I.N., Golosovskii, I.V., Kibalin, Yu.A., Naberezhnov, A.A., Porechnaya, N.I., Pshenko, O.A., and Filimonov, A.V., Structure of magnetic nanoclusters in ferriferous alkali borosilicate glasses, Phys. Solid State, 2012, vol. 54, no. 10, pp. 2106–2112.
Pshenko, O.A., Drozdova, I.A., Polyakova, I.G., Rogacki, K., Ciżman, A., Poprawski, R., Rysiakiewicz-Pasek E., and Antropova T. V. Ferromagnetic iron-containing porous glasses, Glass Phys. Chem., 2014, vol. 40, no. 2, pp. 167–172.
Pshenko, O.A., Antropova, T.V., Lapshin, A.E., Kostyreva, T.G., and Kurilenko, L.N., New vitreous nanocomposites containing the Fe3O4 and γ-KNO3 phases, in Sbornik tezisov Rossiiskoi konferentsii s mezhdunarodnym uchastiem “Steklo: Nauka i praktika.” Sankt-Peterburg, 2013 (Abstracts of Papers of the Russian Conference with the International Participation “Glass: Science and Practice,” St. Petersburg, Russia, November 6–8, 2013), St. Petersburg, 2013, pp. 134–135.
Pshenko, O.A., Arsent’ev, M.Yu., Antropova, T.V., Lapschin, A.E., and Anfimova, I.N., Nanocomposites “Porous Glass—KNO3”: Structure and electric properties, in Abstract Book of the 17th International Zeolite Conference (17th IZC), Moscow, Russia, July 7–12, 2013, Moscow, 2013, pp. 571–572.
Antropova, T., Anfimova, I., Drozdova, I., Polyakova, I., Pshenko, O., Cizżman, A., Rysiakiewicz-Pasek, E., and Poprawski, R., Structure and properties of the ferriferous nano-porous vitreous matrixes, in Book of Abstracts of the 23rd International Congress on Glass, Prague, Czech Republic, July 1–5, 2013, Prague, 2013, pp. 286–287.
Poprawski, R., Cizmźan, A., Pogacki, K., Antropova, T., and Pshenko, O., Physical properties of magnetic porous glass-based multiferroics nanocomposites, in Sbornik tezisov Rossiiskoi konferentsii s mezhdunarodnym uchastiem “Steklo: Nauka i praktika.” Sankt-Peterburg, 2013 (Abstracts of Papers of the Russian Conference with the International Participation “Glass: Science and Practice,” St. Petersburg, November 6–8, 2013), St. Petersburg, 2013, p. 11.
Cizmźan, A., Bednarski, W., Antropova, T.V., Pshenko, O., Rysiakiewicz-Pasek, E., Waplak, S.S., and Poprawski, R., Structural, dielectric, thermal, and electron magnetic resonance studies of magnetic porous glasses filled with ferroelectrics, Composites, Part B, 2014, vol. 64, pp. 16–23.
Nimmo, J.K. and Lucas, B.W., The crystal structures of γ- and β-KNO3 and the a ← γ ← β phase transformations, Acta Crystallogr., Sect. B: Struct. Crystallogr. Cryst. Chem., 1976, vol. 32, no. 7, pp. 1968–1971.
Sawada, S., Nomura, S., and Fujii, S., Ferroelectricity in the phase III of KNO3, J. Phys. Soc. Jpn., 1958, vol. 13, no. 12, pp. 1549–1549.
Jona, F. and Shirane, G., Ferroelectric Crystals, New York: Pergamon, 1962, pp. 360–361.
Antropova, T.V., Anfimova, I.N., Drozdova, I.N., Kostyreva, T.G., Polyakova, I.G., Pshenko, O.A., and Stolyar, S.V., Method for the preparation of a high-silica porous glass with magnetic properties, RF Patent RU 2540754, registered on December 05, 2013; published on February 10, 2015.
Mazurin, O.V., Electrical properties of glass, Tr. Lenigr. Tekhnol. Inst. im. Lensoveta, 1962, no. 62.
Asao, Y., Yoshida, I., Ando, R., and Sawada, S., The electrical resistivities of NaNO2 and KNO3 crystals, J. Phys. Soc. Jpn., 1962, vol. 17, no. 3, pp. 442–446.
Pshenko, O.A., Anfimova, I.N., Kostyreva, T.G., Dikaya, L.F., and Antropova, T.V., Chemical stability of two-phase iron-containing sodium borosilicate glasses in HCl solutions, Fiz. Khim. Stekla, 2012, vol. 38, no. 6, pp. 858–860.
Antropova, T.V. and Drozdova, I.A., Influence of the conditions of preparation of porous glasses on their structure, Glass Phys. Chem., 1995, vol. 21, no. 2, pp. 131–140.
Stolyar, S.V., Pshenko, O.A., Konon, M.Yu., and Antropova, T.V., Electrical conductivity of glasses in the Na2O-B2O3-SiO2-Fe2O3 system, Fiz. Khim. Stekla, 2012, vol. 38, no. 6, pp. 829–831.
Pshenko, O.A., Synthesis and electrical properties of the “porous glass—KNO3 nanocomposites,” in Tezisy dokladov XIII Vserossiiskoi molodezhnoi nauchnoi konferentsii s elementami nauchnoi shkoly “Khimiya silikatov: Vchera, segodnya, zavtra,” Sankt-Peterburg, 2012 (Abstracts of Papers of the 13th All-Russian Youth Scientific Conference with Elements of the Scientific School “Chemistry of Silicates: Yesterday, Today, and Tomorrow,” St. Petersburg, Russia, July 9–10, 2012), St. Petersburg, 2012, pp. 81–84.
Antropova, T.V., Pshenko, O.A., Anfimova, I.N., and Drozdova, I.A., Method for the preparation of a composite multiferroic based on ferromagnetic porous glass, RF Patent Application RU 2015113421, registered on April 14, 2015.
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Original Russian Text © O.A. Pshenko, T.V. Antropova, M.Yu. Arsent’ev, I.A. Drozdova, 2015, published in Fizika i Khimiya Stekla.
The article is based on the lecture presented at the International Conference “Glass: Science and Practice” (November 6–8, 2013, St. Petersburg, Russia).
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Pshenko, O.A., Antropova, T.V., Arsent’ev, M.Y. et al. New vitreous nanocomposites containing phases of Fe3O4 and γ-KNO3 . Glass Phys Chem 41, 509–514 (2015). https://doi.org/10.1134/S1087659615050144
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DOI: https://doi.org/10.1134/S1087659615050144