Abstract
Glass of the K2O–Al2O3–B2O3 system containing Ag, Sb, Ce, KCl, and KBr has been studied. It is shown that an intense additional absorption is induced in this glass by the action of X-ray radiation in the region of 300–400 nm, which is caused by the creation of hole centers. The assumption is expressed that ions of oxygen, chlorine, and bromine included in the environment of the aluninum tetrahedric complex are the donors of electrons generated under the action of X-ray radiation. The hypothesis is proposed about the inclusion of halides in the tetrahedric environment of aluminum (halide effect). It is shown that a red shift of the maximum in the induced absorption spectrum is observed in succession: oxygen, chlorine, and bromine. Ions and nanoparticles of silver, ions of Sb+5, and defects of matrix glass are the acceptors of the induced electrons. The acceptor properties in this succession are increased, which leads to an increase in the induced absorption intensity.
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Skorospelova, V.I. and Stepanov, S.A., Behavior of iron ions in glasses of the K2OAl2O3B2O3 system, Izv. Akad. Nauk SSSR, Neorg. Mater., 1974, vol. 10, no. 3, pp. 1864–1871.
Edelman, I., Ivanova, O., Ivantsov, R., Velikanov, D., Zabluda, V., Zubavichus, Y., Veligzhanin, A., Zaikovskiy, V., Stepanov, S., Artemenko, A., Curely, J., and Kliava, J., Magnetic nanoparticles formed in glasses co-doped with iron and larger radius elements, J. Appl. Phys., 2012, vol. 112, pp. 084331–14.
Golubkov, V.V., Kim, A.A., Nikonorov, N.V., and Shershnev, P.S., Precipitation of nanosized crystals CuBr and CuCl in potassium aluminoborate glasses, Glass Phys. Chem., 2012, vol. 38, no. 3, pp. 259–268.
Kim, A.A., Shirshnev, P.S., Sidorov, A.I., Nikonorov, N.V., and Tsekhomskii, V.A., Nonlinear optical effects in glasses containing copper chloride nanocrystals, Tech. Phys. Lett., 2011, vol. 37, no. 5, pp. 401–403.
Bishey, A., Radiation-induced color centers in multicomponent glasses, J. Non-Cryst. Solids, 2007, vol. 3, pp. 54–114.
Dmitryuk, A.V., Paramzina, S.E., Savvina, O.Ch., and Yashchirzhinskaya, O.A., Investigation of the nature of radiophotoluminescence centers in phosphate glasses activated with silver, Opt. Spektrosk., 1989, vol. 66, no. 5, pp. 1070–1075.
Bondarenko, E.G. and Kabanov, V.O., Luminescence of phosphate glasses activated with silver, Zh. Prikl. Khim., 1981, vol. 35, no. 1, pp. 60–66.
Nikonorov, N.V., Sidorov, A.I., and Tsekhomskii, V.A., in Silver Nanoparticles, Perez, D.P., Ed., Vukovar, Croatia: In-Tech, 2010, pp. 177–200.
Vlasova, N.I., Galant, E.I., and Kefeli, A.A., Spectrophotometric method for the determination of the coordination of boron and aluminum in some glasses, Zh. Neorg. Khim., 1960, vol. 5, no. 8, pp. 1768–1773.
Nikonorov, N. and Tsekhomsky, V., Spectral and photosensitive properties of silver-doped glasses, in Properties and Structure of Oxide Glasses, Klyuev, V.P. and Pevzner, B.Z., Eds., Kerala, India: Research Signpost, 2010, pp. 143–159.
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Original Russian Text © D. Avramenko, N.V. Nikonorov, S.A. Stepanov, V.A. Tsekhomskii, 2015, published in Fizika i Khimiya Stekla.
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Avramenko, D., Nikonorov, N.V., Stepanov, S.A. et al. Effect of X-ray radiation on a potassium aluminaborate glass system. Glass Phys Chem 41, 478–483 (2015). https://doi.org/10.1134/S108765961505003X
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DOI: https://doi.org/10.1134/S108765961505003X