Skip to main content
SpringerLink
Log in

Sol-gel synthesis and properties of compositions containing heteropoly compounds in porous silica matrix

  • Published:
Glass Physics and Chemistry Aims and scope Submit manuscript

Abstract

Compositions containing heteropoly compounds (ammonium phosphoromolybdate (APM) and phosphoromolybdenum acic (PMA)) are synthesized in a porous silica matrix using the sol-gel method. The obtained compositions containing 5–20 w/w % of APM and PMA are studied with the help of the X-ray-phase and differential-thermal analyses, IR and electron spectroscopy, and nitrogen adsorption. The APM and PMA maintain the Keggin structure after being introduced into an oxide matrix. The samples prepared by the sol-gel method have mesoporous and meso-macroporous structures and enhanced photocatalytic activity in comparison to the initial heteropoly compounds.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Tretyakov, Yu.D., Lukashin, A.V., and Eliseev, A.A., Synthesis of functional nanocomposites based on solidphase nanoreactors, Russ. Chem. Rev., 2004, vol. 73, no. 9, pp. 899–922.

    Article  Google Scholar 

  2. Alcoutlabi, M. and McKenna, G.B., Effects of confinement on material behavior at the nanometer size scale, J. Phys.: Condens. Matter, 2005, vol. 17, pp. R461–R524.

    Google Scholar 

  3. Burt, M.C. and Dave, B.C., Externally dynamic confinement effect in organosilica sol-gels, J. Am. Chem. Soc., 2006, vol. 128, pp. 11750–11751.

    Article  Google Scholar 

  4. Pope, M.T. and Müller, A., Polyoxometalate chemistry: An old field with new dimensions in several disciplines, Angew. Chem., Int. Ed. Engl., 1991, vol. 30, pp. 34–48.

    Article  Google Scholar 

  5. Okuhara, T., Mizuno, N., and Misono, M., Catalytic chemistry of heteropoly compounds, Adv. Catal., 1996, vol. 41, pp. 113–252.

    Article  Google Scholar 

  6. Moffat, J.B., Metal-Oxygen Clusters: The Surface and Catalytic Properties of Heteropoly Oxometalates (Fundamental and Applied Catalysis), New York: Kluwer Academic/Plenum, 2001.

    Google Scholar 

  7. Cavani, F., Mezzogori, R., Pigamo, A., Trifiro, F., and Etienne, E., Main aspect of the selective oxidation of isobutene to methacrylic acid catalyzed by Keggin-type polyoxometalates, Catal. Today, 2001, vol. 71, pp. 97–110.

    Article  Google Scholar 

  8. Kormali, P., Troupis, A., Triantis, T., Hiskia, A., and Papaconstantinou, E., Photocatalysis by polyoxometalates and TiO2: A comparative study, Catal. Today, 2007, vol. 124, nos. 3–4, pp. 149–155.

    Article  Google Scholar 

  9. Sydorchuk, V., Zazhigalov, V., Khalameida, S., Skubiszewska-Zięba, J., Charmas, B., and Leboda, R., Deposition of tungsten heteropolycompounds on activated silica surface, Colloids Surf., A, 2009, vol. 341, nos. 1–3, pp. 53–59.

    Article  Google Scholar 

  10. Mrowiec-Bialon, J., Turek, W., and Jarzebski, A.B., Preparation of highly active heteropolyacid-silica composite catalyst using the sol-gel method, React. Kinet. Catal. Lett., 2002, vol. 76, no. 2, pp. 213–219.

    Article  Google Scholar 

  11. Zhang, T.R., Feng, W., Bao, C.Y., Lu, R., Zhang, X.T., Li, T.J., and Zhao, Y.Y., Fabrication of heteropolyoxometalate-based photochromic inorganic-organic nanocomposites, J. Mater. Sci., 2001, vol. 16, pp. 252–263.

    Google Scholar 

  12. Khimich, N.N., Synthesis of silica gels and organicinorganic hybrids on their base, Glass Phys. Chem., 2004, vol. 30, no. 5, pp. 430–442.

    Article  Google Scholar 

  13. Khimich, N.N., Zdravkov, A.V., Koptelova, N.A., Poddenezhnyi, E.N., and Boiko, A.A., sol-gel synthesis of compact nanohybrid structures based on silica gels, Glass Phys. Chem., 2009, vol. 35, no. 2, pp. 181–190.

    Article  Google Scholar 

  14. Goncharik, V.P., Kozhara, L.I., and Zub, Yu.L., Acidic-basic properties of 3-aminopropyl-containing silica gels, Khim., Fiz. Tekhnol. Poverkhn., 2008, no. 14, pp. 248–256.

    Google Scholar 

  15. Popa, A., Sasca, V., Stefanescu, M., Kiš, E.E., and Marinković-Nedučin, R., The influence of the nature and textural properties of different supports on the thermal behavior of Keggin-type heteropolyacids, J. Serb. Chem. Soc., 2006, vol. 71, pp. 235–249.

    Article  Google Scholar 

  16. Youn, M.H., Kim, Y., Jung, J.C., Song, I.K., Barteau, K.P., and Barteau, M.A., UV-vis spectroscopy studies of H3PMo12 − x WxO40 heteropolyacid (HPA) catalysts in the solid state: Effects of water content and polyatom substitution, J. Mol. Catal. A, 2005, vol. 241, pp. 227–232.

    Article  Google Scholar 

  17. Cavani, F., Mezzogori, R., Pigamo, A., and Trifiro, F., Improved catalytic performance of Keggin-type polyoxometalates in the oxidation of isobutene to methacrylic acid under hydrocarbon-lean conditions using antimony-doped catalysts, Chem. Eng. J., 2001, vol. 82, nos. 1–3, pp. 33–42.

    Article  Google Scholar 

  18. Juang, L.-C., Wang, C.-C., and Lee, C.-K., Adsorption of basic dyes onto MCM-41, Chemosphere, 2006, vol. 64, pp. 1920–1928.

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Sorbtion and Problems of Endoecology, National Academy of Sciences of Ukraine, ul. Generala Naumova 13, Kiev, 164, Ukraine

    S. V. Khalameida, V. V. Sydorchuk & V. A. Zazhigalov

  2. Faculty of Chemistry, Department of Chromatographic Methods, Maria Curie-Sklodowska University, Lublin, Poland

    J. Skubiszewska-Zięba & R. Leboda

Authors
  1. S. V. Khalameida
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. V. V. Sydorchuk
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. J. Skubiszewska-Zięba
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. R. Leboda
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. V. A. Zazhigalov
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to S. V. Khalameida.

Additional information

Original Russian Text © S.V. Khalameida, V.V. Sydorchuk, J. Skubiszewska-Zięba, R. Leboda, V.A. Zazhigalov, 2014, published in Fizika i Khimiya Stekla.

Published from the Proceedings of the II International Conference of the CIS “Sol-Gel Synthesis and Study of Inorganic Compounds, Hybrid Functional Materials, and Disperse Systems,” held in Sevastopol’, Ukraine, on September, 18–20, 2012.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Khalameida, S.V., Sydorchuk, V.V., Skubiszewska-Zięba, J. et al. Sol-gel synthesis and properties of compositions containing heteropoly compounds in porous silica matrix. Glass Phys Chem 40, 8–16 (2014). https://doi.org/10.1134/S108765961401009X

Download citation

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S108765961401009X

Keywords

Search

Navigation