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Interpenetrating polymer networks based on polyurethane and organic-inorganic copolymer

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Abstract

The investigation of the features of the formation of interpenetrating polymer networks (IPNs) based on cross-linked polyurethane and organic-inorganic copolymer (OIC) based on hydroxyethyl methacrylate (HEMA) and titanium isopropoxide (Ti(OPri)4) was carried out using the IR spectroscopy method. It has been demonstrated that during the synthesis of organic-inorganic IPNs (OI IPNs), three-dimensional cross-linked structures with the inclusion of (-TiO2-) fragments in the polymer chain of poly(hydroxyethyl methacrylate) are formed. The examinations of the viscoelastic properties and thermal stability of organic-inorganic IPNs by dynamic mechanical (DMA) and thermogravimetric analysis (TGA) showed that the value of M c decreases with an increase in the content of (-TiO2-) fragments in OI IPN; in addition, the thermal stability of the obtained hybrid OI IPNs increases significantly compared to the parent systems.

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Authors and Affiliations

  1. Institute of Macromolecular Chemistry, National Academy of Sciences of Ukraine, Khar’kovskoe sh. 48, Kiev, 02160, Ukraine

    T. T. Alekseeva, I. S. Martynyuk, N. V. Babkina & G. Ya. Menzheres

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  1. T. T. Alekseeva
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  2. I. S. Martynyuk
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  3. N. V. Babkina
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  4. G. Ya. Menzheres
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Correspondence to T. T. Alekseeva.

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Original Russian Text © T.T. Alekseeva, I.S. Martynyuk, N.V. Babkina, G.Ya. Menzheres, 2014, published in Fizika i Khimiya Stekla.

Published from the Proceedings of the II International Conference of the CIS “Sol-Gel Synthesis and Study of Inorganic Compounds, Hybrid Functional Materials, and Disperse Systems,” held in Sevastopol’, Ukraine, on September, 18–20, 2012.

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Alekseeva, T.T., Martynyuk, I.S., Babkina, N.V. et al. Interpenetrating polymer networks based on polyurethane and organic-inorganic copolymer. Glass Phys Chem 40, 17–25 (2014). https://doi.org/10.1134/S1087659614010039

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