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Synthesis and thermoelectric properties of ceramics based on barium-strontium metaplumbates

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Abstract

Ceramics with composition Ba1 − x Sr x Pb1 + y O3 + 2y (x = 0.6, 0.8; y = 0.0, 0.1, 0.2) was synthesized by solid-state method; its phase composition, crystal structure, and thermal, electrophysical, and thermoelectric properties were studied. The electronic and lattice contributions to thermal conductivity of the ceramics were separated; the linear thermal expansion coefficient (LTEC, α), power factor (P), and thermoelectric quality factor (ZT) were calculated. Ceramics with composition Ba0.2Sr0.8Pb1 + y O3 + 2y (P 1000 = 1.36 mW m−1 K−2 for y = 0.1, ZT 423 = 0.033 for y = 0.2) containing lead oxide impurity, in addition to the major phase (barium-strontium metaplumbate), was found to possess the best thermoelectric properties.

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Authors and Affiliations

  1. Belarussian State Technological University, ul. Sverdlova 13a, Minsk, 220050, Belarus

    E. A. Chizhova & A. I. Klyndyuk

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  1. E. A. Chizhova
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  2. A. I. Klyndyuk
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Correspondence to E. A. Chizhova.

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Original Russian Text © E.A. Chizhova, A.I. Klyndyuk, 2013, published in Fizika i Khimiya Stekla.

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Chizhova, E.A., Klyndyuk, A.I. Synthesis and thermoelectric properties of ceramics based on barium-strontium metaplumbates. Glass Phys Chem 39, 453–457 (2013). https://doi.org/10.1134/S1087659613040068

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  • DOI: https://doi.org/10.1134/S1087659613040068

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