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Mass spectrometry study of glasses based on sulfur, phosphorus, and arsenic

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Abstract

The mass spectrometry study of chalcogenide glasses in the P-S binary system and P-As-S ternary system is used to demonstrate that the composition of the gas phase in binary samples is characterized by the conventional spectra of ions, such as PS +2 , P2S +7 , P2S +7 and P4S +10 . The introduction of As to the binary glass systems first demonstrated the presence of ions AsPS+, AsPS +4 , AS2 +5 and As2PS5 + in the gas phase of the ternary chalcogenide system, which correspond to the ternary compositions AsPS4 and As2P2S7 in the solid phase.

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Authors and Affiliations

  1. St. Petersburg State Technical University, St. Petersburg, Russia

    L. N. Blinov

  2. Ioffe Physicotechnical Institute, Russian Academy of Sciences, St. Petersburg, Russia

    V. I. Karataev

Authors
  1. L. N. Blinov
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  2. V. I. Karataev
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Correspondence to L. N. Blinov.

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Original Russian Text © L.N. Blinov, V.I. Karataev, 2013, published in Fizika i Khimiya Stekla.

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Blinov, L.N., Karataev, V.I. Mass spectrometry study of glasses based on sulfur, phosphorus, and arsenic. Glass Phys Chem 39, 358–363 (2013). https://doi.org/10.1134/S1087659613040020

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  • DOI: https://doi.org/10.1134/S1087659613040020

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