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Mixed alkali-zinc diphosphates: Synthesis, structure, and properties

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Abstract

A series of mixed alkali-zinc diphosphates in the form of poly- and single crystals have been synthesized. Their physical-chemical, structural, and thermal characteristics have been determined. The compounds Na2ZnP2O7 and K2ZnP2O7 have a layered structural type, whereas LiNaZnP2O7, LiKZnP2O7, NaKZnP2O7, Li12Zn4(P2O7)5, and K2Zn3(P2O7)2 have a framework structural type.

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Authors and Affiliations

  1. Grebenshchikov Institute of Silicate Chemistry, Russian Academy of Sciences, nab. Makarova 2, St. Petersburg, 199034, Russia

    A. E. Lapshin & M. A. Petrova

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  1. A. E. Lapshin
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  2. M. A. Petrova
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Correspondence to A. E. Lapshin.

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Original Russian Text ¢ A.E. Lapshin, M.A. Petrova, 2012, published in Fizika i Khimiya Stekla.

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Lapshin, A.E., Petrova, M.A. Mixed alkali-zinc diphosphates: Synthesis, structure, and properties. Glass Phys Chem 38, 491–503 (2012). https://doi.org/10.1134/S108765961206003X

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