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Titanium coordination in TiO2-Na2O-SiO2 glasses of xTiO2 · (100 − x) [2Na2O · 3SiO2] (0 ≤ x ≤ 30) composition based on Raman spectroscopy

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Abstract

The structural position of Ti4+ ions in TiO2-Na2O-SiO2 glasses of xTiO2 · (100 − x) [2Na2O · 3SiO2] (0 ≤ x ≤ 30) composition has been studied with Raman spectroscopy. The analysis of spectra recorded has demonstrated that Ti4+ ions in the studied glasses can be in two structural groups—TiO5 and TiO6. Titanium ions with a coordination number of 5 are present in the structure of all Ti-containing glasses, whereas the highly coordinated state exists at x > 10 mol % TiO2.

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References

  1. Emili, M., Incoccia, I., Mobilio, S., Fagherazzi, G., and Guglielmi, M., Structural Investigations of TiO2-SiO2 Glassy and Glass-Ceramic Materials Prepared by Sol-Gel Method, J. Non-Cryst. Solids, 1985, vol. 74, pp. 129–146.

    Article  CAS  Google Scholar 

  2. Kusabiraki, K., Infrared and Raman Spectra of Vitreous Silica and Sodium Silicates Containing Titanium, J. Non-Cryst. Solids, 1987, vols. 95–96, pp. 411–418.

    Article  Google Scholar 

  3. Harada, H., Kamiya, K., and Nasu, H., Structure of Sol-Gel-Derived Sodium Dititanate Glass, J. Sol-Gel Sci. Technol., 1997, vol. 10, pp. 291–300.

    Article  CAS  Google Scholar 

  4. Henderson, G.S., The Structure of Silicate Melts: AGlass Perspective, Can. Mineral., 2005, vol. 43, pp. 1921–1958.

    Article  CAS  Google Scholar 

  5. Henderson, G.S. and Fleet, M.E., The Structure of Ti Silicate Glasses by Micro-Raman Spectroscopy, Can. Mineral., 1995, vol. 33, pp. 399–408.

    CAS  Google Scholar 

  6. Ponader, C.W., Boek, H., and Dickinson, J.E.J., X-Ray Absorption Study of the Coordination of Titanium in Sodium Titanium Silicate Glasses, J. Non-Cryst. Solids, 1996, vol. 201, pp. 81–94.

    Article  CAS  Google Scholar 

  7. Yarker, C.A., Johnson, P.A.V., Wright, A.C., Wono, J., Greegor, R.B., Lytle, F.W., and Sinclair, R.N., Neutron Diffraction and EXAFS Evidence for TiO5 Units in Vitreous K2O · TiO2 · 2SiO2, J. Non-Cryst. Solids, 1986, vol. 79, pp. 117–136.

    Article  CAS  Google Scholar 

  8. Tiwari, B., Pandey, M., Sudarsan, V., Deb, S.K., and Kothiyal, G.P., Study of Structural Modification of Sodium Aluminophosphate Glasses with TiO2 Addition through Raman and NMR Spectroscopy, Phys. B (Amsterdam, Neth.), 2009, vol. 404, pp. 47–51.

    CAS  Google Scholar 

  9. Bykov, V.N., Osipov, A.A., and Anfilogov, V.N., A High-Temperature Spectrometer for Recording Raman Scattering Spectra of Melts, Rasplavy, 1997, no. 4, pp. 28–31.

  10. McMillan, P., Structural Studies of Silicate Glasses and Melts-Applications and Limitations of Raman Spectroscopy, Am. Mineral., 1984, vol. 69, pp. 622–644.

    CAS  Google Scholar 

  11. Lazarev, A.N., Mirgorodskii, A.P., and Smirnov, M.B., Kolebatel’nye spektry i dinamika ionno-kovalentnykh kristallov (Vibrational Spectra and Dynamics of Ionic-Covalent Crystals), Leningrad: Nauka, 1985 [in Russian].

    Google Scholar 

  12. Mysen, B.O., Relationships between Silicate Melt Structure and Petrologic Processes, Earth-Sci. Rev., 1990, vol. 27, pp. 281–365.

    Article  Google Scholar 

  13. Mysen, B.O. and Frantz, J.D., Raman Spectroscopy of Silicate Melts at Magmatic Temperature: Na2O-SiO2, K2O-SiO2, and Li2O-SiO2 Binary Compositions in the Temperature Range 2–1783°C, Chem. Geol., 1992, vol. 96, pp. 321–332.

    Article  CAS  Google Scholar 

  14. Anfilogov, V.N., Bykov, V.N., and Osipov, A.A., Silikatnye rasplavy (Silicate Melts), Moscow: Nauka, 2005 [in Russian].

    Google Scholar 

  15. Malfait, W.J., Zakaznova-Herzog, V.P., Halter, W.E., Quantitative Raman Spectroscopy: Speciation of Na-Silicate Glasses and Melts, Am. Mineral., 2008, vol. 93, pp. 1505–1518.

    Article  CAS  Google Scholar 

  16. Wren, A.W., Kidari, A., Cummins, N.M., and Towler, M.R., A Spectroscopic Investigation into the Setting and Mechanical Properties of Titanium-Containing Glass Polyalkenoate Cements, J. Mater Sci. Mater Med., 2010, vol. 21, pp. 2355–2364.

    Article  CAS  Google Scholar 

  17. Matson, P.W., Sharma, S.K., and Philpotts, J.A., The Structure of High-Silica Alkali-Silicate Glasses: A Raman Spectroscopic Investigation, J. Non-Cryst. Solids, 1983, vol. 58, no. 5, pp. 323–352.

    Article  Google Scholar 

  18. Aguiar, H., Serra, J., González, P., and Léon, B., Structural Study of Sol-Gel Silicate Glasses by IR and Raman Spectroscopies, J. Non-Cryst. Solids, 2009, vol. 355, no. 8, pp. 475–480.

    Article  Google Scholar 

  19. Sokolov, V.O., Plotnichenko, V.G., and Dianov, E.M., Quantum-Chemical Modeling of Titanium Centers in Titanosilicate Glass, Inorg. Mater., 2006, vol. 42, no. 11, pp. 1273–1288.

    Article  Google Scholar 

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Authors and Affiliations

  1. Institute of Mineralogy, Ural Branch, Russian Academy of Sciences, Miass, Chelyabinsk oblast, 456317, Russia

    A. A. Osipov, G. G. Korinevskaya, L. M. Osipova & V. A. Muftakhov

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  1. A. A. Osipov
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  2. G. G. Korinevskaya
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  3. L. M. Osipova
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  4. V. A. Muftakhov
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Correspondence to A. A. Osipov.

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Original Russian Text © A.A. Osipov, G.G. Korinevskaya, L.M. Osipova, V.A. Muftakhov, 2012, published in Fizika i Khimiya Stekla.

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Osipov, A.A., Korinevskaya, G.G., Osipova, L.M. et al. Titanium coordination in TiO2-Na2O-SiO2 glasses of xTiO2 · (100 − x) [2Na2O · 3SiO2] (0 ≤ x ≤ 30) composition based on Raman spectroscopy. Glass Phys Chem 38, 357–360 (2012). https://doi.org/10.1134/S1087659612040098

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  • DOI: https://doi.org/10.1134/S1087659612040098

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