Skip to main content
Log in

Spectroscopic investigations of Eu3+ and Tb3+: Cadmium lead boro tellurite glasses

  • Published:
Glass Physics and Chemistry Aims and scope Submit manuscript

Abstract

This paper reports on the preparation and spectral properties of europium (Eu3+) and terbium (Tb3+) ions doped cadmium lead boro tellurite (CLBT) glasses. For reference glasses, physical properties have been evaluated. From the [measurements of X-ray diffraction (XRD), glass amorphous nature of these [glasses has been studied. From the emission spectra of Eu3+: CLBT glasses, five [transitions (5 D 07 F 0, 7 F 1, 7 F 2, 7 F 3 and 7 F 4) at 579, 591, 613, 652 and 701 nm are observed with λexci = 392 nm (7 F 05 L 6) and in the case of Tb3+: CLBT glasses, four emission transitions 5 D 4 → (7 F 6, 7 F 5, 7 F 4 and 7 F 3) are observed at 489, 543, 584 and 621nm respectively monitered with λexci = 376 nm (7 F 65 G 6).

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Wang, J.S., Vogel, E.M., and Snitzer, E., Tellurite Glass: A New Candidate for Fiber Devices, Opt. Mater., 1994, vol. 3, no. 3, pp. 187–203.

    Article  CAS  Google Scholar 

  2. Upender, G., Vardhani, C.P., Suresh, S., Awasthi, A.M., and Chandra Mouli, V., Structure Physical and Thermal Properties of WO3-GeO2-TeO2 Glasses, Mater. Chem. Phys., 2010, vol. 121, pp. 335–341.

    Article  CAS  Google Scholar 

  3. Vasant Sathe, Preparation and Characterization of Lead and Zinc Tellurite Glasses, J. Non-Cryst. Solids, 2010, vol. 356, pp. 864–872.

    Article  Google Scholar 

  4. Sharma, Y.K., Surana, S.S.L., Dubedi, R.P., and Joshi, V., Spectroscopic and Radiative Properties of Sm3+-Doped Zinc Fluoride Borophosphate Glasses, Mater. Sci. Eng., B., 2005, vol. 119, pp. 131–135.

    Article  Google Scholar 

  5. Sontakke, A.D., Kaushik Biswas, and Annapurna, K., Concentration-Dependent Luminescence of Tb3+ Ions in High-Calcium Aluminosilicate Glasses, J. Lumin., 2009, vol. 129, pp. 1347–1355.

    Article  CAS  Google Scholar 

  6. Karunakaran, R.T., Marimuthu, K., Babu, S.S., and Arumugam, S., Structural, Optical, and Thermal Studies of Eu3+ Ions in Lithium Fluoroborate Glasses, Solid State Sci., 2009, vol. 11, pp. 1882–1889.

    Article  CAS  Google Scholar 

  7. Basavapoornima, Ch., Jyothi, L., Venkatramu, V., Babu, P., Jayasankar, C.K., Tröster, Th., Sievers, W., and Wortmann, G., Effect of High Pressure on Photoluminescence Properties of Eu3+: K-Ba-Al-Fluorophosphate Glasses, J. Alloys Compd., 2010, vol. 509, pp. 1172–1177.

    Article  Google Scholar 

  8. Chaofeng Zhu, Xiaoluan Liang, Yunxia Yang, and Guorong Chen, Luminescence Properties of Tb-Doped and Tm/Tb/Sm Co-Doped Glasses for LED Applications, J. Lumin., 2010, vol. 130, pp. 74–77.

    Article  CAS  Google Scholar 

  9. Giridhar, P., Sailaja, S., Bhushana Reddy, M., Vemasevana Raju, K., Nageswara Raju, C., and Sudhakar Reddy B., Optical Analysis of Sm3+ and Dy3+ Ions Doped Cadmium Lead Boro Tellurite Glasses, Radiat. Eff. Defects Solids, 2011, vol. 166, no. 3, pp. 233–242.

    Article  CAS  Google Scholar 

  10. Saritha, D., Markandeya, Y., Salagram, M., Vithal, M., Singh, A.K., and Bhikshamaiah, G., Effect of Bi2O3 on Physical, Optical, and Structural Studies of ZnO-Bi2O3-B2O3 Glasses, J. Non-Cryst. Solids, 2008, vol. 354, pp. 5573–5579.

    Article  CAS  Google Scholar 

  11. Bensalem, C., Mortier, M., Vivien, D., and Diaf, M., Thermal and Optical Investigation of EuF3-Doped Lead Fluorogermanate Glasses, J. Non-Cryst. Solids, 2010, vol. 356, pp. 56–64.

    Article  CAS  Google Scholar 

  12. Balda, R., Fernandez, J., De Pablos, A., Fdez Navarro, J.M., and Arriandiaga, M.A., Temperature-Dependent Concentration Quenching and Site-Dependent Effects of Nd3+ Fluorescence in Fluorophosphate Glasses, Phys. Rev. B: Condens. Matter, 1996, vol. 53, no. 9, pp. 5181–5189.

    Article  CAS  Google Scholar 

  13. Tatsuya Yamashita and Yasutake Ohishi, Cooperative Energy Transfer between Tb3+ and Yb3+ Ions Co-Doped in Borosilicate Glass, J. Non-Cryst. Solids, 2008, vol. 354, pp. 1883–1890.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to P. Giridhar.

Additional information

The article is published in the original.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Giridhar, P., Seo, H.J., Sailaja, S. et al. Spectroscopic investigations of Eu3+ and Tb3+: Cadmium lead boro tellurite glasses. Glass Phys Chem 38, 77–84 (2012). https://doi.org/10.1134/S1087659612010075

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1087659612010075

Keywords

Navigation