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Study of the properties of bismuth-borate systems toward low-melting lead-free glasses

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Abstract

Data on glass formation, crystallization, and physicochemical properties in the binary (Bi2O3-B2O3) and ternary (PbO-Bi2O3-B2O3, ZnO-Bi2O3-B2O3, and BaO-Bi2O3-B2O3) systems are presented. The feasibility of glasses with high bismuth oxide content (>80 mol %) is addressed. The formation of a glass network of octahedral [BiO6] structural units rather than [BiO3] ones in such systems is shown.

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Authors and Affiliations

  1. Belarusian State Technological University, ul. Sverdlova 13a, Minsk, 220050, Belarus

    N. M. Bobkova

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  1. N. M. Bobkova
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Correspondence to N. M. Bobkova.

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Original Russian Text © N.M. Bobkova, 2012, published in Fizika i Khimiya Stekla.

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Bobkova, N.M. Study of the properties of bismuth-borate systems toward low-melting lead-free glasses. Glass Phys Chem 38, 180–183 (2012). https://doi.org/10.1134/S108765961201004X

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  • DOI: https://doi.org/10.1134/S108765961201004X

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